Synthesis and molecular structure of lanthanum tris[cyclopentadienylmolybdenotricarbonylate] tetrahydrofuranate, (THF)5 La[CpMo(CO)3 ]3 · THF
A. A. Pasynskii
1
,
Igor L. Eremenko
1
,
G Z Suleimanov
2
,
Yu A Nuriev
2
,
V. E. Shklover
3
,
Yu. T. Struchkov
3
Publication type: Journal Article
Publication date: 1984-04-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The interaction of activated La powder with [CpMo(CO) 3 ] 2 or Hg[CpMo(CO) 3 ] 2 in THF resulted in the formation of crystalline (THF) 5 La[CpMo(CO) 3 ] 3 · THF (I), which oxidized readily on exposure to air with cleavage of [CpMo(CO) 3 ) 2 . Complex I was characterized by X-ray structural analysis. The La atom is bound to three equivalent CpMo(CO) 3 fragments via almost linear carbonyl bridges, MoCOLa (MoCO 177.9(7)°). The coordination of La with the terminal CO group (LaO av 2.444(5) A) leads to elongation of the CO bond from an average value of 1.16(1) to 1.21(1) A, and to shortening of the MoC bond from an average value of 1.943(9) to 1.874(9) A, compared with the unbridged CO. The coordination of La is complemented to CN = 8 at the expense of binding of five THF molecules (LaO(THF) av = 2.580(6) A; the sixth THF molecule is crystallizable).
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Pasynskii A. A. et al. Synthesis and molecular structure of lanthanum tris[cyclopentadienylmolybdenotricarbonylate] tetrahydrofuranate, (THF)5La[CpMo(CO)3]3 · THF // Journal of Organometallic Chemistry. 1984. Vol. 266. No. 1. pp. 45-52.
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Pasynskii A. A., Eremenko I. L., Suleimanov G. Z., Nuriev Yu. A., Beletskaya I. P., Shklover V. E., Struchkov Y. T. Synthesis and molecular structure of lanthanum tris[cyclopentadienylmolybdenotricarbonylate] tetrahydrofuranate, (THF)5La[CpMo(CO)3]3 · THF // Journal of Organometallic Chemistry. 1984. Vol. 266. No. 1. pp. 45-52.
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TY - JOUR
DO - 10.1016/0022-328X(84)80109-6
UR - https://doi.org/10.1016/0022-328X(84)80109-6
TI - Synthesis and molecular structure of lanthanum tris[cyclopentadienylmolybdenotricarbonylate] tetrahydrofuranate, (THF)5La[CpMo(CO)3]3 · THF
T2 - Journal of Organometallic Chemistry
AU - Pasynskii, A. A.
AU - Eremenko, Igor L.
AU - Suleimanov, G Z
AU - Nuriev, Yu A
AU - Beletskaya, Irina P.
AU - Shklover, V. E.
AU - Struchkov, Yu. T.
PY - 1984
DA - 1984/04/01
PB - Elsevier
SP - 45-52
IS - 1
VL - 266
SN - 0022-328X
SN - 1872-8561
ER -
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@article{1984_Pasynskii,
author = {A. A. Pasynskii and Igor L. Eremenko and G Z Suleimanov and Yu A Nuriev and Irina P. Beletskaya and V. E. Shklover and Yu. T. Struchkov},
title = {Synthesis and molecular structure of lanthanum tris[cyclopentadienylmolybdenotricarbonylate] tetrahydrofuranate, (THF)5La[CpMo(CO)3]3 · THF},
journal = {Journal of Organometallic Chemistry},
year = {1984},
volume = {266},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/0022-328X(84)80109-6},
number = {1},
pages = {45--52},
doi = {10.1016/0022-328X(84)80109-6}
}
Cite this
MLA
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Pasynskii, A. A., et al. “Synthesis and molecular structure of lanthanum tris[cyclopentadienylmolybdenotricarbonylate] tetrahydrofuranate, (THF)5La[CpMo(CO)3]3 · THF.” Journal of Organometallic Chemistry, vol. 266, no. 1, Apr. 1984, pp. 45-52. https://doi.org/10.1016/0022-328X(84)80109-6.