Antiferromagnetic complexes with a metal-metal bond. XI. Synthesis and structure of the pentanuclear cyclopentadienyl-t-butylthiolate-sulphidechromium cluster [Cp2 Cr2 (μ2 -SCME3 )(μ3 -S)2 ]2 Cr with a "bow-tie" frame
A. A. Pasynskii
1
,
Igor L. Eremenko
1
,
B Orazsakhatov
1
,
G Sh Gasanov
1
,
V. E. Shklover
2
,
Yu. T. Struchkov
2
Publication type: Journal Article
Publication date: 1984-07-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The reaction of the binuclear complex Cp 2 Cr 2 (SCMe 3 ) 2 S (I) with C 6 H 6 Cr(CO) 3 in a benzene/heptane ( 1 2 ) mixture under UV irradiation yields black crystals of the cluster [Cp 2 Cr 2 (SCMe 3 )S 2 ] 2 Cr (II), which, according to X-ray data, contains a pentanuclear “bow-tie” frame with a central Cr II atom, the angle between the Cr 3 triangle planes being 90°. The bonds between the central and peripheral chromium atoms are oridinary (2.933(1) and 2.889(1) A), while two pairs of Cr II atoms are double-bonded (CrCr 2.655(1) A). Above and below each Cr 3 triangle is a μ 3 -sulphide bridge (average Cr (centr.) S 2.333(3), average Cr (periph.) S 2.305(3) A). Moreover, the peripheral Cr III atoms are bonded in pairs with a μ 2 -SCMe 3 bridge (average CrS 2.358(4) A), and every Cr III atom is coordinated by a π-cyclopentadienyl ligand (average CrC 2.26(1) A, average CC 1.43(2) A).
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Pasynskii A. A. et al. Antiferromagnetic complexes with a metal-metal bond. XI. Synthesis and structure of the pentanuclear cyclopentadienyl-t-butylthiolate-sulphidechromium cluster [Cp2Cr2(μ2-SCME3)(μ3-S)2]2Cr with a "bow-tie" frame // Journal of Organometallic Chemistry. 1984. Vol. 269. No. 2. pp. 147-153.
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Pasynskii A. A., Eremenko I. L., Orazsakhatov B., Gasanov G. S., Shklover V. E., Struchkov Y. T. Antiferromagnetic complexes with a metal-metal bond. XI. Synthesis and structure of the pentanuclear cyclopentadienyl-t-butylthiolate-sulphidechromium cluster [Cp2Cr2(μ2-SCME3)(μ3-S)2]2Cr with a "bow-tie" frame // Journal of Organometallic Chemistry. 1984. Vol. 269. No. 2. pp. 147-153.
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TY - JOUR
DO - 10.1016/0022-328X(84)80292-2
UR - https://doi.org/10.1016/0022-328X(84)80292-2
TI - Antiferromagnetic complexes with a metal-metal bond. XI. Synthesis and structure of the pentanuclear cyclopentadienyl-t-butylthiolate-sulphidechromium cluster [Cp2Cr2(μ2-SCME3)(μ3-S)2]2Cr with a "bow-tie" frame
T2 - Journal of Organometallic Chemistry
AU - Pasynskii, A. A.
AU - Eremenko, Igor L.
AU - Orazsakhatov, B
AU - Gasanov, G Sh
AU - Shklover, V. E.
AU - Struchkov, Yu. T.
PY - 1984
DA - 1984/07/01
PB - Elsevier
SP - 147-153
IS - 2
VL - 269
SN - 0022-328X
SN - 1872-8561
ER -
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@article{1984_Pasynskii,
author = {A. A. Pasynskii and Igor L. Eremenko and B Orazsakhatov and G Sh Gasanov and V. E. Shklover and Yu. T. Struchkov},
title = {Antiferromagnetic complexes with a metal-metal bond. XI. Synthesis and structure of the pentanuclear cyclopentadienyl-t-butylthiolate-sulphidechromium cluster [Cp2Cr2(μ2-SCME3)(μ3-S)2]2Cr with a "bow-tie" frame},
journal = {Journal of Organometallic Chemistry},
year = {1984},
volume = {269},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/0022-328X(84)80292-2},
number = {2},
pages = {147--153},
doi = {10.1016/0022-328X(84)80292-2}
}
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Pasynskii, A. A., et al. “Antiferromagnetic complexes with a metal-metal bond. XI. Synthesis and structure of the pentanuclear cyclopentadienyl-t-butylthiolate-sulphidechromium cluster [Cp2Cr2(μ2-SCME3)(μ3-S)2]2Cr with a "bow-tie" frame.” Journal of Organometallic Chemistry, vol. 269, no. 2, Jul. 1984, pp. 147-153. https://doi.org/10.1016/0022-328X(84)80292-2.
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