The polarity of XH and XM bonds in compounds of the ArXH and ArXM (X = O, S, NR; M = Hg, Sn, Pb, Sb) types and their capacity for coordination and dissociation
Publication type: Journal Article
Publication date: 1984-12-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The relationship between the values of the σR+ constants of the XMRn and XH groups, reflecting the polarity of the XM and XH bonds, and the capacity of these bonds for heterolytic dissociation in DMSO have been analysed. Linear relations have been established between σR+ and log Kd. The factors responsible for the abnormal stability of the SHg and SPb bonds are discussed. It has been shown that the capacity of the XM and XH bonds for dissociation is not determined by the force of the coordination interactions (Kc) between the M or H atoms and DMSO. The parallel pattern of variations in σR+ and Kc is observed only in the case of XH acids and their SnPh3 and PbPh3 derivatives.
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Epstein L. M. et al. The polarity of XH and XM bonds in compounds of the ArXH and ArXM (X = O, S, NR; M = Hg, Sn, Pb, Sb) types and their capacity for coordination and dissociation // Journal of Organometallic Chemistry. 1984. Vol. 277. No. 2. pp. 153-158.
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Epstein L. M., Shubina Y. S., Ashkinadze L. D., Kravtsov D. The polarity of XH and XM bonds in compounds of the ArXH and ArXM (X = O, S, NR; M = Hg, Sn, Pb, Sb) types and their capacity for coordination and dissociation // Journal of Organometallic Chemistry. 1984. Vol. 277. No. 2. pp. 153-158.
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TY - JOUR
DO - 10.1016/0022-328X(84)80696-8
UR - https://doi.org/10.1016/0022-328X(84)80696-8
TI - The polarity of XH and XM bonds in compounds of the ArXH and ArXM (X = O, S, NR; M = Hg, Sn, Pb, Sb) types and their capacity for coordination and dissociation
T2 - Journal of Organometallic Chemistry
AU - Epstein, L M
AU - Shubina, Ye S
AU - Ashkinadze, L D
AU - Kravtsov, D.N.
PY - 1984
DA - 1984/12/01
PB - Elsevier
SP - 153-158
IS - 2
VL - 277
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1984_Epstein,
author = {L M Epstein and Ye S Shubina and L D Ashkinadze and D.N. Kravtsov},
title = {The polarity of XH and XM bonds in compounds of the ArXH and ArXM (X = O, S, NR; M = Hg, Sn, Pb, Sb) types and their capacity for coordination and dissociation},
journal = {Journal of Organometallic Chemistry},
year = {1984},
volume = {277},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/0022-328X(84)80696-8},
number = {2},
pages = {153--158},
doi = {10.1016/0022-328X(84)80696-8}
}
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MLA
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Epstein, L. M., et al. “The polarity of XH and XM bonds in compounds of the ArXH and ArXM (X = O, S, NR; M = Hg, Sn, Pb, Sb) types and their capacity for coordination and dissociation.” Journal of Organometallic Chemistry, vol. 277, no. 2, Dec. 1984, pp. 153-158. https://doi.org/10.1016/0022-328X(84)80696-8.
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