Antiferromagnetic complexes with a metal-metal bond
Igor L. Eremenko
1
,
A. A. Pasynskii
1
,
G Sh Gasanov
1
,
B Orazsakhatov
1
,
Yu. T. Struchkov
2
,
V. E. Shklover
2
Publication type: Journal Article
Publication date: 1984-10-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The antiferromagnetic cluster [Cp 2 Cr 2 (SCMe 3 )(μ 3 -S) 2 ] 2Mn (II) was obtained by reaction of (CpCrSCMe 3 ) 2 S with CpMn(CO) 3 (reagent ratio 2:1) under UV irradiation in boiling toluene. The structure of II was established by an X-ray structural study. Crystals of II are orthorhombic, space group F dd 2, a = 39.715(13), b = 21.127(7), c = 7.808(3) A, V = 6551.4 A 3 , Z = 8. The molecule of II has a symmetrical bow-tie metal framework Cr 4 Mn with short CrCr bonds (2.690(4) A) and elongated CrMn bonds (2.936(3) and 2.947(3) A). The angle between the planes of Cr 2 Mn triangles is equal to 90°. The central Mn II atom ( d 5 electron configuration) is situated on a crystallographic two-fold axis and, besides Cr atoms, is surrounded by four μ 3 -bridging sulphur atoms (MnS, 2.393(5) and 2.389(5) A). Both CrCr bonds are bridged by a tert-butylthiolate group (av. CrS 2.347(5) A).
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Eremenko I. L. et al. Antiferromagnetic complexes with a metal-metal bond // Journal of Organometallic Chemistry. 1984. Vol. 275. No. 2. pp. 183-189.
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Eremenko I. L., Pasynskii A. A., Gasanov G. S., Orazsakhatov B., Struchkov Y. T., Shklover V. E. Antiferromagnetic complexes with a metal-metal bond // Journal of Organometallic Chemistry. 1984. Vol. 275. No. 2. pp. 183-189.
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RIS
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TY - JOUR
DO - 10.1016/0022-328X(84)85053-6
UR - https://doi.org/10.1016/0022-328X(84)85053-6
TI - Antiferromagnetic complexes with a metal-metal bond
T2 - Journal of Organometallic Chemistry
AU - Eremenko, Igor L.
AU - Pasynskii, A. A.
AU - Gasanov, G Sh
AU - Orazsakhatov, B
AU - Struchkov, Yu. T.
AU - Shklover, V. E.
PY - 1984
DA - 1984/10/01
PB - Elsevier
SP - 183-189
IS - 2
VL - 275
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1984_Eremenko,
author = {Igor L. Eremenko and A. A. Pasynskii and G Sh Gasanov and B Orazsakhatov and Yu. T. Struchkov and V. E. Shklover},
title = {Antiferromagnetic complexes with a metal-metal bond},
journal = {Journal of Organometallic Chemistry},
year = {1984},
volume = {275},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/0022-328X(84)85053-6},
number = {2},
pages = {183--189},
doi = {10.1016/0022-328X(84)85053-6}
}
Cite this
MLA
Copy
Eremenko, Igor L., et al. “Antiferromagnetic complexes with a metal-metal bond.” Journal of Organometallic Chemistry, vol. 275, no. 2, Oct. 1984, pp. 183-189. https://doi.org/10.1016/0022-328X(84)85053-6.
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