Antiferromagnetic complexes with a metalmetal bond. XVII. Synthesis and molecular structures of the antiferromagnetic clusters (Cp2 Cr2 SCMe3 )(η3 -S)2 RhL2 (L2 = π-C8 H12 or (CO)2 ) with long CrRh bonds
A. A. Pasynskii
1
,
Igor L. Eremenko
1
,
V R Zalmanovich
1
,
V V Kaverin
1
,
B Orazsakhatov
1
,
V. M. Novotortsev
1
,
O.G Ellert
1
,
A. I. Yanovsky
2
,
Yu. T. Struchkov
2
Publication type: Journal Article
Publication date: 1988-11-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of Cp2Cr2(η-SCMe3)2(η-S) (I) with (π-C8H12RhCl)2 or (acac)Rh(CO)2 in benzene, which leads to the mixed-metal clusters Cp2Cr2(η-SCMe3) (η3-S)2RhL2(II, L = 1 2 π-C8H12; III, L CO) have been studied. The structures of the antiferromagnetic clusters II and III were determined by X-ray diffraction study (II: space grop P 1 − , a 9.913(8), b 13.994(11), c 18.242(12) A; α 91.96(3), β 95.91(2), γ 106.24(2)°, Z = 4, two independent molecules; III: space group Pbca, a 16.966(5), b 13.190(5), c 17.885(6) A, Z = 8). Long CrRh (3.064(1)–3.009(1) A in II 3.3134–3.010 A in III) and short CrCr bonds (2.687(1) A in Ii and 2.708(1) A in III) were observed in both triangular metal clusters. In II and III the two S atoms and the ligands L are in square planar coordination which is typical of RhI atoms.
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Pasynskii A. A. et al. Antiferromagnetic complexes with a metalmetal bond. XVII. Synthesis and molecular structures of the antiferromagnetic clusters (Cp2Cr2SCMe3)(η3-S)2RhL2 (L2 = π-C8H12 or (CO)2) with long CrRh bonds // Journal of Organometallic Chemistry. 1988. Vol. 356. No. 1. pp. 57-65.
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Pasynskii A. A., Eremenko I. L., Zalmanovich V. R., Kaverin V. V., Orazsakhatov B., Novotortsev V. M., Ellert O., Yanovsky A. I., Struchkov Y. T. Antiferromagnetic complexes with a metalmetal bond. XVII. Synthesis and molecular structures of the antiferromagnetic clusters (Cp2Cr2SCMe3)(η3-S)2RhL2 (L2 = π-C8H12 or (CO)2) with long CrRh bonds // Journal of Organometallic Chemistry. 1988. Vol. 356. No. 1. pp. 57-65.
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TY - JOUR
DO - 10.1016/0022-328X(88)80673-9
UR - https://doi.org/10.1016/0022-328X(88)80673-9
TI - Antiferromagnetic complexes with a metalmetal bond. XVII. Synthesis and molecular structures of the antiferromagnetic clusters (Cp2Cr2SCMe3)(η3-S)2RhL2 (L2 = π-C8H12 or (CO)2) with long CrRh bonds
T2 - Journal of Organometallic Chemistry
AU - Pasynskii, A. A.
AU - Eremenko, Igor L.
AU - Zalmanovich, V R
AU - Kaverin, V V
AU - Orazsakhatov, B
AU - Novotortsev, V. M.
AU - Ellert, O.G
AU - Yanovsky, A. I.
AU - Struchkov, Yu. T.
PY - 1988
DA - 1988/11/01
PB - Elsevier
SP - 57-65
IS - 1
VL - 356
SN - 0022-328X
SN - 1872-8561
ER -
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@article{1988_Pasynskii,
author = {A. A. Pasynskii and Igor L. Eremenko and V R Zalmanovich and V V Kaverin and B Orazsakhatov and V. M. Novotortsev and O.G Ellert and A. I. Yanovsky and Yu. T. Struchkov},
title = {Antiferromagnetic complexes with a metalmetal bond. XVII. Synthesis and molecular structures of the antiferromagnetic clusters (Cp2Cr2SCMe3)(η3-S)2RhL2 (L2 = π-C8H12 or (CO)2) with long CrRh bonds},
journal = {Journal of Organometallic Chemistry},
year = {1988},
volume = {356},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/0022-328X(88)80673-9},
number = {1},
pages = {57--65},
doi = {10.1016/0022-328X(88)80673-9}
}
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MLA
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Pasynskii, A. A., et al. “Antiferromagnetic complexes with a metalmetal bond. XVII. Synthesis and molecular structures of the antiferromagnetic clusters (Cp2Cr2SCMe3)(η3-S)2RhL2 (L2 = π-C8H12 or (CO)2) with long CrRh bonds.” Journal of Organometallic Chemistry, vol. 356, no. 1, Nov. 1988, pp. 57-65. https://doi.org/10.1016/0022-328X(88)80673-9.
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