Journal of Organometallic Chemistry

, volume 356 , issue 2 , pages 181-193

1,3-Di-t-butyl substituted cyclopentadienyl Titanium complexes. New structural aspects

I F Urazowski ¹

V I Ponomaryov ¹

O.G Ellert ²

I E Nifaniev ³

D A Lemenovskii ³

Hide authors affiliations Show authors affiliations: 3 affiliations

Institute of Chemical Physics U.S.S.R. Academy of Sciences, Chernogolovka U.S.S.R. | |

Institute of General and Inorganic Chemistry U.S.S.R. Academy of Sciences, Moscow U.S.S.R. | |

Chemistry Department, University of Moscow, Moscow U.S.S.R. | |

Publication type: Journal Article

Publication date: 1988-11-01

Elsevier

Journal of Organometallic Chemistry

scimago Q3

wos Q2

SJR: 0.385

CiteScore: 4.1

Impact factor: 2.4

ISSN: 0022328X, 18728561

DOI: 10.1016/0022-328X(88)83088-2

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Materials Chemistry

Organic Chemistry

Biochemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

Abstract Cp**2TiCl2 (I) was obtained by the reaction of TiCl4 with Cp**LiC5H3(C4-H9-t)2Li. Complex I was treated with potassium metal in pentane to give paramagnetic Cp**2TiCl (II) in high yield. The crystal structures of I and II were determined by X-ray crystallography. The molecules of both complexes are monomeric in crystals. Complex I: monoclinic, B2/b, a 21.069, b 19.387, c 6.560 A, γ 94.25°, R = 0.045. TiCl and TiC bond distances are 2.349 and 2.124 A, on the average, respectively. ClTiCl and Cp***TiTp** angle values are 93.1 and 121° Complex II: monoclinic, P2/n, a 13.497, b 13.441, c 7.207 A, γ 86.48°, R = 0.064 TiCl and TiC bond distances are 2.337 and 2.386 A, on the average, respectively. Cp***TiCp** angle value is 134.8°.

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Urazowski I. F. et al. 1,3-Di-t-butyl substituted cyclopentadienyl Titanium complexes. New structural aspects // Journal of Organometallic Chemistry. 1988. Vol. 356. No. 2. pp. 181-193.

GOST all authors (up to 50) Copy

Urazowski I. F., Ponomaryov V. I., Ellert O., Nifaniev I. E., Lemenovskii D. A. 1,3-Di-t-butyl substituted cyclopentadienyl Titanium complexes. New structural aspects // Journal of Organometallic Chemistry. 1988. Vol. 356. No. 2. pp. 181-193.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/0022-328X(88)83088-2

UR - https://linkinghub.elsevier.com/retrieve/pii/0022328X88830882

TI - 1,3-Di-t-butyl substituted cyclopentadienyl Titanium complexes. New structural aspects

T2 - Journal of Organometallic Chemistry

AU - Urazowski, I F

AU - Ponomaryov, V I

AU - Ellert, O.G

AU - Nifaniev, I E

AU - Lemenovskii, D A

PY - 1988

DA - 1988/11/01

PB - Elsevier

SP - 181-193

IS - 2

VL - 356

SN - 0022-328X

SN - 1872-8561

ER -

BibTex |

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@article{1988_Urazowski,

author = {I F Urazowski and V I Ponomaryov and O.G Ellert and I E Nifaniev and D A Lemenovskii},

title = {1,3-Di-t-butyl substituted cyclopentadienyl Titanium complexes. New structural aspects},

journal = {Journal of Organometallic Chemistry},

year = {1988},

volume = {356},

publisher = {Elsevier},

month = {nov},

url = {https://linkinghub.elsevier.com/retrieve/pii/0022328X88830882},

number = {2},

pages = {181--193},

doi = {10.1016/0022-328X(88)83088-2}

}

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Urazowski, I. F., et al. “1,3-Di-t-butyl substituted cyclopentadienyl Titanium complexes. New structural aspects.” Journal of Organometallic Chemistry, vol. 356, no. 2, Nov. 1988, pp. 181-193. https://linkinghub.elsevier.com/retrieve/pii/0022328X88830882.