ansa-Metallocene derivatives of TiIV and ZrIV with the shortest C(CH3 )2 bridge
Publication type: Journal Article
Publication date: 1992-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Novel C(CH3)2 bridged molecules, (CH3)2C(C5H4)2M(CH3)2, M = Ti, Zr, were synthesized. The structures of both molecules were determined by X-ray diffraction analysis. For the Ti compound: crystals, monoctinic; space group, P21, / m, a = 7.196(4), b = 10.227(1), c = 8.941(3) A, γ = 89.95°. For Zr compound: crystals, monoclinic; space group P21 / m, a = 7.333(4), b = 10.429(3), c = 9.031(6) A, γ = 89.98°. Both molecules are characterized, as expected, by significant intramolecular tension resulting in obvious distortion of the sandwich moiety.
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Nifant'ev I. E. et al. ansa-Metallocene derivatives of TiIV and ZrIV with the shortest C(CH3)2 bridge // Journal of Organometallic Chemistry. 1992. Vol. 435. No. 1-2. pp. 37-42.
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Nifant'ev I. E., Churakov A. V., Urazowski I. F., Mkoyan S. G., Atovmyan L. ansa-Metallocene derivatives of TiIV and ZrIV with the shortest C(CH3)2 bridge // Journal of Organometallic Chemistry. 1992. Vol. 435. No. 1-2. pp. 37-42.
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RIS
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TY - JOUR
DO - 10.1016/0022-328X(92)83458-T
UR - https://linkinghub.elsevier.com/retrieve/pii/0022328X9283458T
TI - ansa-Metallocene derivatives of TiIV and ZrIV with the shortest C(CH3)2 bridge
T2 - Journal of Organometallic Chemistry
AU - Nifant'ev, Ilya E.
AU - Churakov, Andrei V.
AU - Urazowski, I F
AU - Mkoyan, Sh G
AU - Atovmyan, L.O
PY - 1992
DA - 1992/02/01
PB - Elsevier
SP - 37-42
IS - 1-2
VL - 435
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1992_Nifant'ev,
author = {Ilya E. Nifant'ev and Andrei V. Churakov and I F Urazowski and Sh G Mkoyan and L.O Atovmyan},
title = {ansa-Metallocene derivatives of TiIV and ZrIV with the shortest C(CH3)2 bridge},
journal = {Journal of Organometallic Chemistry},
year = {1992},
volume = {435},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/0022328X9283458T},
number = {1-2},
pages = {37--42},
doi = {10.1016/0022-328X(92)83458-T}
}
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MLA
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Nifant'ev, Ilya E., et al. “ansa-Metallocene derivatives of TiIV and ZrIV with the shortest C(CH3)2 bridge.” Journal of Organometallic Chemistry, vol. 435, no. 1-2, Feb. 1992, pp. 37-42. https://linkinghub.elsevier.com/retrieve/pii/0022328X9283458T.
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