Antiferromagnetic complexes with metal-metal bonds
A. A. Pasynskii
1
,
Igor L. Eremenko
1
,
S.E. Nefedov
1
,
B Orazsakhatov
1
,
A.A. Zharkikh
1
,
O.G Ellert
1
,
V. M. Novotortsev
1
,
A. I. Yanovsky
2
,
Yu. T. Struchkov
2
Publication type: Journal Article
Publication date: 1993-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract The antiferromagnetic complex CP 2 Cr 2 (μ-SCMe 3 ) 2 (μ 3 -S)Re 2 (CO) 9 ( II ) (−2 J =424 cm −1 ) was obtained by photochemical reaction of CP 2 Cr 2 (μ-SCMe 3 ) 2 (μ-S) ( I ) with Re 2 (CO) 10 in benzene-THF; the dirhenium moiety within complex II (ReRe 3.0691(8) A) is only bound to the framework of complex I through coordination of the rhenium atom by the sulfide bridge (ReS 2.555(2) A). It is shown that under more rigorous conditions ( hv , m -xylene, 144°) the reaction proceeds with cleavage of the ReRe bond and formation of a 66e antiferromagnetic cluster Cp 2 Cr 2 (μ 3 -SCMe 3 ) 2 (μ 3 -S) 2 Re 2 (CO) 6 ( III ) (−2 J = 302 cm − ) with a distorted cubane core Cr 2 Re 2 S 4 (CrS 2.32(1), CrSR 2.39 (2), ReS 2.590(8), ReSR 2.514(8)-2.534(7) A) which only contains a CrCr bond (CrCr 2.96(1), Cr ... Re 3.645(1) and 3.646(1), Re ... Re 3.938(1) A).
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Pasynskii A. A. et al. Antiferromagnetic complexes with metal-metal bonds // Journal of Organometallic Chemistry. 1993. Vol. 444. No. 1-2. pp. 101-105.
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Pasynskii A. A., Eremenko I. L., Nefedov S., Orazsakhatov B., Zharkikh A., Ellert O., Novotortsev V. M., Yanovsky A. I., Struchkov Y. T. Antiferromagnetic complexes with metal-metal bonds // Journal of Organometallic Chemistry. 1993. Vol. 444. No. 1-2. pp. 101-105.
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TY - JOUR
DO - 10.1016/0022-328X(93)83061-Y
UR - https://doi.org/10.1016/0022-328X(93)83061-Y
TI - Antiferromagnetic complexes with metal-metal bonds
T2 - Journal of Organometallic Chemistry
AU - Pasynskii, A. A.
AU - Eremenko, Igor L.
AU - Nefedov, S.E.
AU - Orazsakhatov, B
AU - Zharkikh, A.A.
AU - Ellert, O.G
AU - Novotortsev, V. M.
AU - Yanovsky, A. I.
AU - Struchkov, Yu. T.
PY - 1993
DA - 1993/02/01
PB - Elsevier
SP - 101-105
IS - 1-2
VL - 444
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1993_Pasynskii,
author = {A. A. Pasynskii and Igor L. Eremenko and S.E. Nefedov and B Orazsakhatov and A.A. Zharkikh and O.G Ellert and V. M. Novotortsev and A. I. Yanovsky and Yu. T. Struchkov},
title = {Antiferromagnetic complexes with metal-metal bonds},
journal = {Journal of Organometallic Chemistry},
year = {1993},
volume = {444},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/0022-328X(93)83061-Y},
number = {1-2},
pages = {101--105},
doi = {10.1016/0022-328X(93)83061-Y}
}
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MLA
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Pasynskii, A. A., et al. “Antiferromagnetic complexes with metal-metal bonds.” Journal of Organometallic Chemistry, vol. 444, no. 1-2, Feb. 1993, pp. 101-105. https://doi.org/10.1016/0022-328X(93)83061-Y.
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