том 452 издание 1-2 страницы 87-90

Synthesis and structure of η1-N-diphenyldiazomethane complexes of niobo- and tantalocene monohydrides

Тип публикацииJournal Article
Дата публикации1993-06-01
scimago Q3
wos Q2
БС2
SJR0.385
CiteScore4.1
Impact factor2.4
ISSN0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Abstract Interaction of niobo- and tantalocene trihydrides (Cp2 MH3; M  Nb, Ta) with diphenyldiazomethane under mild conditions leads to monohydride complexes of a new type, Cp2 M(H) (η1-NNCPh2), where M  Nb I and Ta II. I and II have been characterized by a 1H NMR study, and I also by an X-ray single crystal diffraction study at 183 K (R = 0.029 for 1510 reflections). The molecule of I is of a bent sandwich type with the distances NbCp(plane) of 2.13 (A, NbN 1.850 (A) (multiple bond), NbH 1.65 (A) and HNBN angle of 94°.
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ГОСТ |
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Nikonov G. I. et al. Synthesis and structure of η1-N-diphenyldiazomethane complexes of niobo- and tantalocene monohydrides // Journal of Organometallic Chemistry. 1993. Vol. 452. No. 1-2. pp. 87-90.
ГОСТ со всеми авторами (до 50) Скопировать
Nikonov G. I., Putala M., Zinin A. I., Kazennova N. B., Lemenovskii D. A., Batsanov A. S., Struchkov Y. T. Synthesis and structure of η1-N-diphenyldiazomethane complexes of niobo- and tantalocene monohydrides // Journal of Organometallic Chemistry. 1993. Vol. 452. No. 1-2. pp. 87-90.
RIS |
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TY - JOUR
DO - 10.1016/0022-328X(93)83176-V
UR - https://linkinghub.elsevier.com/retrieve/pii/0022328X9383176V
TI - Synthesis and structure of η1-N-diphenyldiazomethane complexes of niobo- and tantalocene monohydrides
T2 - Journal of Organometallic Chemistry
AU - Nikonov, G. I.
AU - Putala, Martin
AU - Zinin, A I
AU - Kazennova, N B
AU - Lemenovskii, D A
AU - Batsanov, A. S.
AU - Struchkov, Yu. T.
PY - 1993
DA - 1993/06/01
PB - Elsevier
SP - 87-90
IS - 1-2
VL - 452
SN - 0022-328X
SN - 1872-8561
ER -
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@article{1993_Nikonov,
author = {G. I. Nikonov and Martin Putala and A I Zinin and N B Kazennova and D A Lemenovskii and A. S. Batsanov and Yu. T. Struchkov},
title = {Synthesis and structure of η1-N-diphenyldiazomethane complexes of niobo- and tantalocene monohydrides},
journal = {Journal of Organometallic Chemistry},
year = {1993},
volume = {452},
publisher = {Elsevier},
month = {jun},
url = {https://linkinghub.elsevier.com/retrieve/pii/0022328X9383176V},
number = {1-2},
pages = {87--90},
doi = {10.1016/0022-328X(93)83176-V}
}
MLA
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Nikonov, G. I., et al. “Synthesis and structure of η1-N-diphenyldiazomethane complexes of niobo- and tantalocene monohydrides.” Journal of Organometallic Chemistry, vol. 452, no. 1-2, Jun. 1993, pp. 87-90. https://linkinghub.elsevier.com/retrieve/pii/0022328X9383176V.