Hydrogen-bonded complexes involving the metal atom and protonation of metallocenes of the iron subgroup
Publication type: Journal Article
Publication date: 1994-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The interactions were studied of metallocenes and their permethylated analogues of the iron subgroup (M = Fe, Ru, Os) with trifluoroacetic acid in low-polar media. IR and UV-Vis spectra, over a wide temperature range, proved that formation of the molecular hydrogen-bonded complex (OH ⋯ M) is the first stage of protonation. The ionic H-complexes of the M + H ⋯ O − type are formed as a result of proton transfer. The influences of the metal, the substituents on the Cp-ring and of the concentration of acid on this acid-base equilibrium are discussed.
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31
Total citations:
31
Citations from 2024:
1
(3.23%)
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GOST
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Shubina E. S. et al. Hydrogen-bonded complexes involving the metal atom and protonation of metallocenes of the iron subgroup // Journal of Organometallic Chemistry. 1994. Vol. 465. No. 1-2. pp. 259-262.
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Shubina E. S., Krylov A., Kreindlin A. Z., Rybinskaya M. I., Epstein L. M. Hydrogen-bonded complexes involving the metal atom and protonation of metallocenes of the iron subgroup // Journal of Organometallic Chemistry. 1994. Vol. 465. No. 1-2. pp. 259-262.
Cite this
RIS
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TY - JOUR
DO - 10.1016/0022-328X(94)87063-2
UR - https://doi.org/10.1016/0022-328X(94)87063-2
TI - Hydrogen-bonded complexes involving the metal atom and protonation of metallocenes of the iron subgroup
T2 - Journal of Organometallic Chemistry
AU - Shubina, Elena S.
AU - Krylov, A.N.
AU - Kreindlin, A Z
AU - Rybinskaya, M. I.
AU - Epstein, L M
PY - 1994
DA - 1994/02/01
PB - Elsevier
SP - 259-262
IS - 1-2
VL - 465
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{1994_Shubina,
author = {Elena S. Shubina and A.N. Krylov and A Z Kreindlin and M. I. Rybinskaya and L M Epstein},
title = {Hydrogen-bonded complexes involving the metal atom and protonation of metallocenes of the iron subgroup},
journal = {Journal of Organometallic Chemistry},
year = {1994},
volume = {465},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/0022-328X(94)87063-2},
number = {1-2},
pages = {259--262},
doi = {10.1016/0022-328X(94)87063-2}
}
Cite this
MLA
Copy
Shubina, Elena S., et al. “Hydrogen-bonded complexes involving the metal atom and protonation of metallocenes of the iron subgroup.” Journal of Organometallic Chemistry, vol. 465, no. 1-2, Feb. 1994, pp. 259-262. https://doi.org/10.1016/0022-328X(94)87063-2.
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