The molecular structure of 1-fluorosilatrane
1
Central Research Institute of Chemistry of the Hungarian Academy of Sciences, H-1525 Budapest, P.O. Box 17, Hungary
|
Publication type: Journal Article
Publication date: 1984-07-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The crystal structure of 1-fluorosilatrane has been determined by X-ray diffraction. The N → Si dative bond length is 2.042(1) A, somewhat longer than that in the 1-chloro derivative (2.023 A). The carbon atoms linked to nitrogen are disordered. The atoms in the close-packed crystal structure are well fixed and have low thermal motion. Deformation electron density calculations show considerable density in the region between the silicon and nitrogen atoms. A mass spectrometric study indicates a strong SiF bond.
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66
Total citations:
66
Citations from 2025:
2
(3.03%)
Cite this
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RIS |
BibTex |
MLA
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GOST
Copy
Párkányi L. et al. The molecular structure of 1-fluorosilatrane // Journal of Organometallic Chemistry. 1984. Vol. 269. No. 1. pp. 1-9.
GOST all authors (up to 50)
Copy
Párkányi L., Hencsei P., Bihátsi L., Müller T. The molecular structure of 1-fluorosilatrane // Journal of Organometallic Chemistry. 1984. Vol. 269. No. 1. pp. 1-9.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0022-328X(84)80270-3
UR - https://doi.org/10.1016/0022-328X(84)80270-3
TI - The molecular structure of 1-fluorosilatrane
T2 - Journal of Organometallic Chemistry
AU - Párkányi, László
AU - Hencsei, Pál
AU - Bihátsi, László
AU - Müller, Tibor
PY - 1984
DA - 1984/07/01
PB - Elsevier
SP - 1-9
IS - 1
VL - 269
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1984_Párkányi,
author = {László Párkányi and Pál Hencsei and László Bihátsi and Tibor Müller},
title = {The molecular structure of 1-fluorosilatrane},
journal = {Journal of Organometallic Chemistry},
year = {1984},
volume = {269},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/0022-328X(84)80270-3},
number = {1},
pages = {1--9},
doi = {10.1016/0022-328X(84)80270-3}
}
Cite this
MLA
Copy
Párkányi, László, et al. “The molecular structure of 1-fluorosilatrane.” Journal of Organometallic Chemistry, vol. 269, no. 1, Jul. 1984, pp. 1-9. https://doi.org/10.1016/0022-328X(84)80270-3.