Efficient palladium catalysts for the carbonylation of alkynes
1
Koninklijke/Shell-Laboratorium, Amsterdam (Shell Research B.V.) Badhuisweg 3, NL-1031 CM Amsterdam Netherlands
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Publication type: Journal Article
Publication date: 1993-08-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A class of highly efficient homogeneous palladium catalysts has been developed for the carbonylation of alkynes. One application of interest is the selective production of methyl methacrylate by methoxycarbonylation of propyne. The essential feature of the new catalyst systems is that they are formed by the combination of a ligand containing a 2-pyridylphosphine moiety with a palladium(II) species and a proton source containing weakly coordinating anions. High turn-over numbers of more than 40000 mol (mol Pd)−1 h−1 and selectivities towards methyl methacrylate of up to 99.95% can be obtained under mild conditions. It is suggested that the 2-pyridylphosphine ligand plays an essential role both as a chelating PN ligand in the selectivity-determining step and as a monocoordinated ligand in the rate-determining step of the catalytic cycle.
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249
Total citations:
249
Citations from 2025:
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(4.02%)
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GOST
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Drent E., Arnoldy P., Budzelaar P. H. M. Efficient palladium catalysts for the carbonylation of alkynes // Journal of Organometallic Chemistry. 1993. Vol. 455. No. 1-2. pp. 247-253.
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Drent E., Arnoldy P., Budzelaar P. H. M. Efficient palladium catalysts for the carbonylation of alkynes // Journal of Organometallic Chemistry. 1993. Vol. 455. No. 1-2. pp. 247-253.
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TY - JOUR
DO - 10.1016/0022-328X(93)80406-2
UR - https://linkinghub.elsevier.com/retrieve/pii/0022328X93804062
TI - Efficient palladium catalysts for the carbonylation of alkynes
T2 - Journal of Organometallic Chemistry
AU - Drent, E.
AU - Arnoldy, P
AU - Budzelaar, P. H. M.
PY - 1993
DA - 1993/08/01
PB - Elsevier
SP - 247-253
IS - 1-2
VL - 455
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{1993_Drent,
author = {E. Drent and P Arnoldy and P. H. M. Budzelaar},
title = {Efficient palladium catalysts for the carbonylation of alkynes},
journal = {Journal of Organometallic Chemistry},
year = {1993},
volume = {455},
publisher = {Elsevier},
month = {aug},
url = {https://linkinghub.elsevier.com/retrieve/pii/0022328X93804062},
number = {1-2},
pages = {247--253},
doi = {10.1016/0022-328X(93)80406-2}
}
Cite this
MLA
Copy
Drent, E., et al. “Efficient palladium catalysts for the carbonylation of alkynes.” Journal of Organometallic Chemistry, vol. 455, no. 1-2, Aug. 1993, pp. 247-253. https://linkinghub.elsevier.com/retrieve/pii/0022328X93804062.