Journal of Organometallic Chemistry, volume 463, issue 1-2, pages 215-221
Synthesis, characterization and reactivity of [Rh(bpy)(C2H4)Cl]. A study on the reaction with C1 molecules (CH2O, CO2) and NaBPh4
1
Dipartimento di Chimica, Campus Universitario, 70126, Bari Italy
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Publication type: Journal Article
Publication date: 1993-12-01
Journal:
Journal of Organometallic Chemistry
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 2.3
ISSN: 0022328X
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The synthesis, spectroscopic characterization and reactivity of [Rh(bpy)(C 2 H 4 )Cl] ( 1 ) (bpy = 2,2′-bipyridine) are reported. Compound 1 reacts with CH 2 O to afford the known carbonyl complex [Rh(bpy)(CO)Cl] ( 3 ). The reaction with CO 2 leads to ethylene carboxylation and gives a propionic acid derivative. The reaction of [Rh(bpy)(C 2 H 4 )Cl] with NaBPh 4 affords the new complex [(bpy) Rh(η 6 -PhBPh 3 )] ( 2 ), a unique example of η 6 -coordinated tetraphenylborate to the “(bpy)Rh” moiety.
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Aresta M. et al. Synthesis, characterization and reactivity of [Rh(bpy)(C2H4)Cl]. A study on the reaction with C1 molecules (CH2O, CO2) and NaBPh4 // Journal of Organometallic Chemistry. 1993. Vol. 463. No. 1-2. pp. 215-221.
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Aresta M., Aresta M., Quaranta E., QUARANTA E. Synthesis, characterization and reactivity of [Rh(bpy)(C2H4)Cl]. A study on the reaction with C1 molecules (CH2O, CO2) and NaBPh4 // Journal of Organometallic Chemistry. 1993. Vol. 463. No. 1-2. pp. 215-221.
Cite this
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TY - JOUR
DO - 10.1016/0022-328X(93)83420-Z
UR - https://doi.org/10.1016/0022-328X(93)83420-Z
TI - Synthesis, characterization and reactivity of [Rh(bpy)(C2H4)Cl]. A study on the reaction with C1 molecules (CH2O, CO2) and NaBPh4
T2 - Journal of Organometallic Chemistry
AU - Aresta, Michele
AU - Quaranta, Eugenio
AU - Aresta, Michele
AU - QUARANTA, E
PY - 1993
DA - 1993/12/01
PB - Elsevier
SP - 215-221
IS - 1-2
VL - 463
SN - 0022-328X
ER -
Cite this
BibTex
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@article{1993_Aresta,
author = {Michele Aresta and Eugenio Quaranta and Michele Aresta and E QUARANTA},
title = {Synthesis, characterization and reactivity of [Rh(bpy)(C2H4)Cl]. A study on the reaction with C1 molecules (CH2O, CO2) and NaBPh4},
journal = {Journal of Organometallic Chemistry},
year = {1993},
volume = {463},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/0022-328X(93)83420-Z},
number = {1-2},
pages = {215--221},
doi = {10.1016/0022-328X(93)83420-Z}
}
Cite this
MLA
Copy
Aresta, Michele, et al. “Synthesis, characterization and reactivity of [Rh(bpy)(C2H4)Cl]. A study on the reaction with C1 molecules (CH2O, CO2) and NaBPh4.” Journal of Organometallic Chemistry, vol. 463, no. 1-2, Dec. 1993, pp. 215-221. https://doi.org/10.1016/0022-328X(93)83420-Z.