Polymerization of 3-alkylthiophenes with FeCl3
1
Neste Oy, Corporate R&D, POB 310, SF-06101 Porvoo, Finland
|
Publication type: Journal Article
Publication date: 1992-01-01
scimago Q1
wos Q2
SJR: 0.843
CiteScore: 7.7
Impact factor: 4.5
ISSN: 00323861, 18732291
Materials Chemistry
Organic Chemistry
Polymers and Plastics
Abstract
We report on the mechanism of direct oxidation of 3-alkylthiophenes using ferric chloride (FeCl3) as the polymerization oxidant/catalyst to produce high molecular weight poly(3-alkylthiophenes) (P3ATs), conjugated polymers that have potential as electrically and optically active polymers. This study shows that the FeCl3 must exist in the solid state in the reaction mixture to be active as an oxidant in the polymerization of P3AT. A feasible polymerization mechanism for 3-alkylthiophene was developed on the basis of the crystal structure of FeCl3 and quantum chemical computations of thiophene derivatives. The polymerization is hypothesized to proceed through a radical mechanism rather than a radical cation mechanism.
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Metrics
149
Total citations:
149
Citations from 2024:
10
(6%)
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GOST
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Niemi V. et al. Polymerization of 3-alkylthiophenes with FeCl3 // Polymer. 1992. Vol. 33. No. 7. pp. 1559-1562.
GOST all authors (up to 50)
Copy
Niemi V., Knuuttila P., Österholm J. E., Korvola J. Polymerization of 3-alkylthiophenes with FeCl3 // Polymer. 1992. Vol. 33. No. 7. pp. 1559-1562.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0032-3861(92)90138-M
UR - https://doi.org/10.1016/0032-3861(92)90138-M
TI - Polymerization of 3-alkylthiophenes with FeCl3
T2 - Polymer
AU - Niemi, V.M.
AU - Knuuttila, P.
AU - Österholm, J E
AU - Korvola, J
PY - 1992
DA - 1992/01/01
PB - Elsevier
SP - 1559-1562
IS - 7
VL - 33
SN - 0032-3861
SN - 1873-2291
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1992_Niemi,
author = {V.M. Niemi and P. Knuuttila and J E Österholm and J Korvola},
title = {Polymerization of 3-alkylthiophenes with FeCl3},
journal = {Polymer},
year = {1992},
volume = {33},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/0032-3861(92)90138-M},
number = {7},
pages = {1559--1562},
doi = {10.1016/0032-3861(92)90138-M}
}
Cite this
MLA
Copy
Niemi, V.M., et al. “Polymerization of 3-alkylthiophenes with FeCl3.” Polymer, vol. 33, no. 7, Jan. 1992, pp. 1559-1562. https://doi.org/10.1016/0032-3861(92)90138-M.