Solid State Communications, volume 86, issue 10, pages 689-693
High ionic conductivity in lithium lanthanum titanate
Yoshiyuki Inaguma
1
,
Liquan Chen
1
,
Mitsuru Itoh
1
,
T. Nakamura
1
,
Takashi Uchida
2
,
Hiromasa Ikuta
2
,
Masataka Wakihara
2
Publication type: Journal Article
Publication date: 1993-06-01
Journal:
Solid State Communications
Quartile SCImago
Q2
Quartile WOS
Q3
Impact factor: 2.1
ISSN: 00381098
Materials Chemistry
General Chemistry
Condensed Matter Physics
Abstract
It has been discovered that the polycrystalline lithium lanthanum titanate Li0.34(1)La0.51(1)TiO2.94(2) shows high ionic conductivity more than 2 × 10−5 S cm−1 (D.C. method) at room temperature, which is compared with that of Li3.5V0.5Ge0.5O4. This compound has cubic perovskite structure whose cell parameter is 3.8710(2) A. By a.c. impedance analysis, the equivalent circuit of the sample could be divided into two parts; bulk crystal and grain boundary. The ionic conductivity of the bulk part is as high as 1 × 10−3 S cm−1 at room temperature. Such a high conductivity is considered to be attributed to the presence of a lot of equivalent sites for lithium ion to occupy and freely move in this perovskite. In addition, this compound is easy to react with lithium metal and the electronic conductivity has become much higher than before being in contact with Li. It can be explained that titanium ion was reduced by ii insertion into a vacant site and then an electron carrier was introduced.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Inaguma Y. et al. High ionic conductivity in lithium lanthanum titanate // Solid State Communications. 1993. Vol. 86. No. 10. pp. 689-693.
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Inaguma Y., Chen L., Itoh M., Nakamura T., Uchida T., Ikuta H., Wakihara M. High ionic conductivity in lithium lanthanum titanate // Solid State Communications. 1993. Vol. 86. No. 10. pp. 689-693.
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TY - JOUR
DO - 10.1016/0038-1098(93)90841-A
UR - https://doi.org/10.1016/0038-1098(93)90841-A
TI - High ionic conductivity in lithium lanthanum titanate
T2 - Solid State Communications
AU - Inaguma, Yoshiyuki
AU - Chen, Liquan
AU - Itoh, Mitsuru
AU - Nakamura, T.
AU - Uchida, Takashi
AU - Ikuta, Hiromasa
AU - Wakihara, Masataka
PY - 1993
DA - 1993/06/01 00:00:00
PB - Elsevier
SP - 689-693
IS - 10
VL - 86
SN - 0038-1098
ER -
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@article{1993_Inaguma,
author = {Yoshiyuki Inaguma and Liquan Chen and Mitsuru Itoh and T. Nakamura and Takashi Uchida and Hiromasa Ikuta and Masataka Wakihara},
title = {High ionic conductivity in lithium lanthanum titanate},
journal = {Solid State Communications},
year = {1993},
volume = {86},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/0038-1098(93)90841-A},
number = {10},
pages = {689--693},
doi = {10.1016/0038-1098(93)90841-A}
}
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MLA
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Inaguma, Yoshiyuki, et al. “High ionic conductivity in lithium lanthanum titanate.” Solid State Communications, vol. 86, no. 10, Jun. 1993, pp. 689-693. https://doi.org/10.1016/0038-1098(93)90841-A.