Evidence for cyclohexyne as an intermediate in the coupling of phenyllithium with 1-chlorocyclohexene
Тип публикации: Journal Article
Дата публикации: 1957-01-01
scimago Q3
wos Q2
БС2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Краткое описание
Elimination-Adition mechanisms involving benzyne-type (C_6H_4) intermediates have been established for the rearrangements which occur in the amination of non-activated aryl halides, high temperature alkaline hydrolysis of aryl halides and the coupling of phenyllithium with aryl halides. Wittig and Harboth have reported small yields of 1-phenylcyclohexene from the coupling of phenyllithium with 1-chlorocyclohexene and it appeared possible that this reaction might well proceed by way of cyclohexyne as an intermediate. Of interest in this connection is the report by Favorsky and Boshowsky that a cyclohyexne trimer (dodecahydrotriphenylene) is formed in the reaction of 1,2-dibromocyclohexene with sodium.
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ГОСТ
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Scardiglia F., Roberts J. P. Evidence for cyclohexyne as an intermediate in the coupling of phenyllithium with 1-chlorocyclohexene // Tetrahedron. 1957. Vol. 1. No. 4. pp. 343-344.
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Scardiglia F., Roberts J. P. Evidence for cyclohexyne as an intermediate in the coupling of phenyllithium with 1-chlorocyclohexene // Tetrahedron. 1957. Vol. 1. No. 4. pp. 343-344.
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TY - JOUR
DO - 10.1016/0040-4020(57)88011-9
UR - https://doi.org/10.1016/0040-4020(57)88011-9
TI - Evidence for cyclohexyne as an intermediate in the coupling of phenyllithium with 1-chlorocyclohexene
T2 - Tetrahedron
AU - Scardiglia, F
AU - Roberts, John Paul
PY - 1957
DA - 1957/01/01
PB - Elsevier
SP - 343-344
IS - 4
VL - 1
SN - 0040-4020
SN - 1464-5416
ER -
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BibTex (до 50 авторов)
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@article{1957_Scardiglia,
author = {F Scardiglia and John Paul Roberts},
title = {Evidence for cyclohexyne as an intermediate in the coupling of phenyllithium with 1-chlorocyclohexene},
journal = {Tetrahedron},
year = {1957},
volume = {1},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/0040-4020(57)88011-9},
number = {4},
pages = {343--344},
doi = {10.1016/0040-4020(57)88011-9}
}
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MLA
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Scardiglia, F., and John Paul Roberts. “Evidence for cyclohexyne as an intermediate in the coupling of phenyllithium with 1-chlorocyclohexene.” Tetrahedron, vol. 1, no. 4, Jan. 1957, pp. 343-344. https://doi.org/10.1016/0040-4020(57)88011-9.