Electrochemical cyclodimerization of alkylidenemalonates
M. N. Elinson
1
,
Sergey K. Feducovich
1
,
Alexandre A Zakharenkov
1
,
Bogdan I. Ugrak
1
,
Gennady I. Nikishin
1
,
Sergey Lindeman
2
,
Jurii T Struchkov
2
Publication type: Journal Article
Publication date: 1995-04-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Electrolysis of dimethyl alkylidenemalonates RCH = C(COOMe)2 (R = n−Alk, Ph) in an undivided cell in MeOH in the presence of alkali metal halide as mediator, leads to the formation of cyclic dimers, i.e., 3,4-disubstituted 1,1,2,2-cyclobutanetetracarboxylates. The reaction proceeds via the reductive coupling of two substrate molecules at cathode and the cyclization of a hydrodimer dianion by its interaction with an active form of a mediator, an anode-generated halogen.
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GOST
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Elinson M. N. et al. Electrochemical cyclodimerization of alkylidenemalonates // Tetrahedron. 1995. Vol. 51. No. 17. pp. 5035-5046.
GOST all authors (up to 50)
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Elinson M. N., Feducovich S. K., Zakharenkov A. A., Ugrak B. I., Nikishin G. I., Lindeman S., Struchkov J. T. Electrochemical cyclodimerization of alkylidenemalonates // Tetrahedron. 1995. Vol. 51. No. 17. pp. 5035-5046.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0040-4020(95)98700-R
UR - https://doi.org/10.1016/0040-4020(95)98700-R
TI - Electrochemical cyclodimerization of alkylidenemalonates
T2 - Tetrahedron
AU - Elinson, M. N.
AU - Feducovich, Sergey K.
AU - Zakharenkov, Alexandre A
AU - Ugrak, Bogdan I.
AU - Nikishin, Gennady I.
AU - Lindeman, Sergey
AU - Struchkov, Jurii T
PY - 1995
DA - 1995/04/01
PB - Elsevier
SP - 5035-5046
IS - 17
VL - 51
SN - 0040-4020
SN - 1464-5416
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1995_Elinson,
author = {M. N. Elinson and Sergey K. Feducovich and Alexandre A Zakharenkov and Bogdan I. Ugrak and Gennady I. Nikishin and Sergey Lindeman and Jurii T Struchkov},
title = {Electrochemical cyclodimerization of alkylidenemalonates},
journal = {Tetrahedron},
year = {1995},
volume = {51},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/0040-4020(95)98700-R},
number = {17},
pages = {5035--5046},
doi = {10.1016/0040-4020(95)98700-R}
}
Cite this
MLA
Copy
Elinson, Michail N., et al. “Electrochemical cyclodimerization of alkylidenemalonates.” Tetrahedron, vol. 51, no. 17, Apr. 1995, pp. 5035-5046. https://doi.org/10.1016/0040-4020(95)98700-R.