Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents
Publication type: Journal Article
Publication date: 1995-05-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
The reaction of aryl halides with secondary amines in the presence of silylamide base and tri- o -tolyphopshine palladium complexes gives arylamine products. This process provides a convenient method for performing these hetero-cross coupling reactions without the necessity for forming tin amides and disposing of tin halides. This reaction follows from a mechanistic analysis of the coupling reaction with tin amides and occurs as a result of the cleavage of palladium aryl halide dimers with secondary amines.
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824
Total citations:
824
Citations from 2024:
68
(8.25%)
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GOST
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Louie J., Hartwig J. H. Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents // Tetrahedron Letters. 1995. Vol. 36. No. 21. pp. 3609-3612.
GOST all authors (up to 50)
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Louie J., Hartwig J. H. Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents // Tetrahedron Letters. 1995. Vol. 36. No. 21. pp. 3609-3612.
Cite this
RIS
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TY - JOUR
DO - 10.1016/0040-4039(95)00605-C
UR - https://doi.org/10.1016/0040-4039(95)00605-C
TI - Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents
T2 - Tetrahedron Letters
AU - Louie, Janis
AU - Hartwig, John H
PY - 1995
DA - 1995/05/01
PB - Elsevier
SP - 3609-3612
IS - 21
VL - 36
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
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@article{1995_Louie,
author = {Janis Louie and John H Hartwig},
title = {Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents},
journal = {Tetrahedron Letters},
year = {1995},
volume = {36},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0040-4039(95)00605-C},
number = {21},
pages = {3609--3612},
doi = {10.1016/0040-4039(95)00605-C}
}
Cite this
MLA
Copy
Louie, Janis, and John H Hartwig. “Palladium-catalyzed synthesis of arylamines from aryl halides. Mechanistic studies lead to coupling in the absence of tin reagents.” Tetrahedron Letters, vol. 36, no. 21, May. 1995, pp. 3609-3612. https://doi.org/10.1016/0040-4039(95)00605-C.