Organic conductors based on diradicals: the benzobisdithiazole (BBDT) system
Publication type: Journal Article
Publication date: 1986-05-01
scimago Q1
wos Q2
SJR: 0.787
CiteScore: 8.3
Impact factor: 4.6
ISSN: 03796779
Materials Chemistry
Metals and Alloys
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanical Engineering
Mechanics of Materials
Abstract
The synthesis and full characterization of the title heterocycle are presented. BRDT (1) can be studied in its three stable oxidation states: diradical, radical action and dication. Of these, the diradical exists as an oligomer in solution (compelling evidence for a dimer is presented). E.s.r. spectroscopy of the twolower oxidation states revealed, unexpectedly, but in accord with molecular orbital calculations, that in the radical cation the spin is fully delocalized, whereas in the diradical it is partially localized on only the nitrogen atoms. Coproportionation of the diradical with the dication in a ratio of 3:1 produced the first highly conducting solid based on BBDT.
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Total citations:
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GOST
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Williams K. et al. Organic conductors based on diradicals: the benzobisdithiazole (BBDT) system // Synthetic Metals. 1986. Vol. 14. No. 4. pp. 233-238.
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Williams K., Nowak M. A., Dormann E., Wudl F. Organic conductors based on diradicals: the benzobisdithiazole (BBDT) system // Synthetic Metals. 1986. Vol. 14. No. 4. pp. 233-238.
Cite this
RIS
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TY - JOUR
DO - 10.1016/0379-6779(86)90037-8
UR - https://doi.org/10.1016/0379-6779(86)90037-8
TI - Organic conductors based on diradicals: the benzobisdithiazole (BBDT) system
T2 - Synthetic Metals
AU - Williams, Keith
AU - Nowak, M. A.
AU - Dormann, Elmar
AU - Wudl, F.
PY - 1986
DA - 1986/05/01
PB - Elsevier
SP - 233-238
IS - 4
VL - 14
SN - 0379-6779
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1986_Williams,
author = {Keith Williams and M. A. Nowak and Elmar Dormann and F. Wudl},
title = {Organic conductors based on diradicals: the benzobisdithiazole (BBDT) system},
journal = {Synthetic Metals},
year = {1986},
volume = {14},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0379-6779(86)90037-8},
number = {4},
pages = {233--238},
doi = {10.1016/0379-6779(86)90037-8}
}
Cite this
MLA
Copy
Williams, Keith, et al. “Organic conductors based on diradicals: the benzobisdithiazole (BBDT) system.” Synthetic Metals, vol. 14, no. 4, May. 1986, pp. 233-238. https://doi.org/10.1016/0379-6779(86)90037-8.