Journal of Alloys and Compounds

, том 206 , издание 2 , страницы 185-188

Crystal structure of Ba5In2Al2ZrO13

Тип публикации: Journal Article

Дата публикации: 1994-05-01

Elsevier

Journal of Alloys and Compounds

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SJR: 1.192

CiteScore: 11.8

Impact factor: 6.3

ISSN: 09258388, 18734669

DOI: 10.1016/0925-8388(94)90033-7

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Materials Chemistry

Metals and Alloys

Mechanical Engineering

Mechanics of Materials

Краткое описание

The crystal structure of anion-deficient hexagonal perovskite-like oxide Ba5In2Al2ZrO3 (a = 5.8707(7) A, a = 24.445(3) A, space group P63/mmc, z = 2) was determined using single crystal data. A least-squares refinement gave conventional and weighted R factors of 0.037 and 0.040 respectively. This structure is a 10L (cchcc)2 sequence of close-packed BaO3 and BaO□2 layers. The main feature of the structure is joint occupation of two 4f positions by In and Al atoms, which result in disordering of oxygen atoms and vacancies in the BaO□2 layers. It was shown that this structure can be considered formally as a result of the intergrowth of Ba2InAlO5-like blocks and BaZrO3 ones along the c-axis of the hexagonal supercell.

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Антипов Евгений

д.х.н., проф., академик, Российская академия наук

466 публикаций, 10 708 цитирований, 29 рецензий

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Московский государственный университет имени М.В. Ломоносова

Сколковский институт науки и технологий

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Shpanchenko R. et al. Crystal structure of Ba5In2Al2ZrO13 // Journal of Alloys and Compounds. 1994. Vol. 206. No. 2. pp. 185-188.

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Shpanchenko R., Abakumov A. M., Antipov E. V., Kovba L. M. Crystal structure of Ba5In2Al2ZrO13 // Journal of Alloys and Compounds. 1994. Vol. 206. No. 2. pp. 185-188.

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TY - JOUR

DO - 10.1016/0925-8388(94)90033-7

UR - https://linkinghub.elsevier.com/retrieve/pii/0925838894900337

TI - Crystal structure of Ba5In2Al2ZrO13

T2 - Journal of Alloys and Compounds

AU - Shpanchenko, R.V.

AU - Abakumov, Artem M.

AU - Antipov, Evgeny V.

AU - Kovba, L. M.

PY - 1994

DA - 1994/05/01

PB - Elsevier

SP - 185-188

IS - 2

VL - 206

SN - 0925-8388

SN - 1873-4669

ER -

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@article{1994_Shpanchenko,

author = {R.V. Shpanchenko and Artem M. Abakumov and Evgeny V. Antipov and L. M. Kovba},

title = {Crystal structure of Ba5In2Al2ZrO13},

journal = {Journal of Alloys and Compounds},

year = {1994},

volume = {206},

publisher = {Elsevier},

month = {may},

url = {https://linkinghub.elsevier.com/retrieve/pii/0925838894900337},

number = {2},

pages = {185--188},

doi = {10.1016/0925-8388(94)90033-7}

}

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Shpanchenko, R.V., et al. “Crystal structure of Ba5In2Al2ZrO13.” Journal of Alloys and Compounds, vol. 206, no. 2, May. 1994, pp. 185-188. https://linkinghub.elsevier.com/retrieve/pii/0925838894900337.