An ESR study of benzene radical cation in an argon matrix: Evidence for favourable stabilization of 2B1g rather than 2B2g state
Publication type: Journal Article
Publication date: 1999-02-01
scimago Q2
wos Q2
SJR: 0.546
CiteScore: 5.9
Impact factor: 3.1
ISSN: 00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Abstract Benzene radical cations were generated in an argon matrix by fast electron irradiation at 16 K. The ESR spectrum measured immediately after irradiation results probably from the mixture of the two distorted states; however, it converts irreversibly to the spectrum of the 2 B 1 g state upon annealing. The latter spectrum exhibits major hyperfine coupling with four of six protons (the isotropic coupling constant was estimated to be 0.64 mT). The role of basic Jahn–Teller distortion and matrix-assisted effects for benzene radical cations trapped in low-temperature matrices is discussed.
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Total citations:
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Citations from 2024:
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(4.35%)
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GOST
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Feldman V. I. et al. An ESR study of benzene radical cation in an argon matrix: Evidence for favourable stabilization of 2B1g rather than 2B2g state // Chemical Physics Letters. 1999. Vol. 300. No. 5-6. pp. 713-718.
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Feldman V. I., Sukhov F. F., Orlov A. Y. An ESR study of benzene radical cation in an argon matrix: Evidence for favourable stabilization of 2B1g rather than 2B2g state // Chemical Physics Letters. 1999. Vol. 300. No. 5-6. pp. 713-718.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0009-2614(98)01434-1
UR - https://linkinghub.elsevier.com/retrieve/pii/S0009261498014341
TI - An ESR study of benzene radical cation in an argon matrix: Evidence for favourable stabilization of 2B1g rather than 2B2g state
T2 - Chemical Physics Letters
AU - Feldman, Vladimir I.
AU - Sukhov, F F
AU - Orlov, A. Yu.
PY - 1999
DA - 1999/02/01
PB - Elsevier
SP - 713-718
IS - 5-6
VL - 300
SN - 0009-2614
SN - 1873-4448
ER -
Cite this
BibTex (up to 50 authors)
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@article{1999_Feldman,
author = {Vladimir I. Feldman and F F Sukhov and A. Yu. Orlov},
title = {An ESR study of benzene radical cation in an argon matrix: Evidence for favourable stabilization of 2B1g rather than 2B2g state},
journal = {Chemical Physics Letters},
year = {1999},
volume = {300},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0009261498014341},
number = {5-6},
pages = {713--718},
doi = {10.1016/S0009-2614(98)01434-1}
}
Cite this
MLA
Copy
Feldman, Vladimir I., et al. “An ESR study of benzene radical cation in an argon matrix: Evidence for favourable stabilization of 2B1g rather than 2B2g state.” Chemical Physics Letters, vol. 300, no. 5-6, Feb. 1999, pp. 713-718. https://linkinghub.elsevier.com/retrieve/pii/S0009261498014341.
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