volume 331 issue 2-4 pages 243-252

Dipolar spectroscopy and spin alignment in electron paramagnetic resonance

Publication typeJournal Article
Publication date2000-12-01
scimago Q2
wos Q2
SJR0.546
CiteScore5.9
Impact factor3.1
ISSN00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Two single-frequency techniques for refocusing (SIFTER) dipolar couplings between electron spins are introduced. The experiments are based on the solid-echo and Jeener–Broekaert sequences, well established in dipolar NMR spectroscopy of solids, and open up new routes to high-resolution two-dimensional EPR spectroscopy with only moderate requirements on the spectrometer. For distances between paramagnetic centres larger than 3 nm, SIFTER provides better resolution than double electron–electron resonance (DEER). Good agreement between distances from SIFTER measurements and force-field computations is found for shape-persistent biradicals with distances up to 5.1 nm corresponding to a dipolar frequency of 390 kHz.
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GOST |
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GOST Copy
Jeschke G. et al. Dipolar spectroscopy and spin alignment in electron paramagnetic resonance // Chemical Physics Letters. 2000. Vol. 331. No. 2-4. pp. 243-252.
GOST all authors (up to 50) Copy
Jeschke G., Pannier M., Godt A., Spiess H. Dipolar spectroscopy and spin alignment in electron paramagnetic resonance // Chemical Physics Letters. 2000. Vol. 331. No. 2-4. pp. 243-252.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/S0009-2614(00)01171-4
UR - https://doi.org/10.1016/S0009-2614(00)01171-4
TI - Dipolar spectroscopy and spin alignment in electron paramagnetic resonance
T2 - Chemical Physics Letters
AU - Jeschke, Gunnar
AU - Pannier, M.
AU - Godt, A.
AU - Spiess, H.W.
PY - 2000
DA - 2000/12/01
PB - Elsevier
SP - 243-252
IS - 2-4
VL - 331
SN - 0009-2614
SN - 1873-4448
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2000_Jeschke,
author = {Gunnar Jeschke and M. Pannier and A. Godt and H.W. Spiess},
title = {Dipolar spectroscopy and spin alignment in electron paramagnetic resonance},
journal = {Chemical Physics Letters},
year = {2000},
volume = {331},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/S0009-2614(00)01171-4},
number = {2-4},
pages = {243--252},
doi = {10.1016/S0009-2614(00)01171-4}
}
MLA
Cite this
MLA Copy
Jeschke, Gunnar, et al. “Dipolar spectroscopy and spin alignment in electron paramagnetic resonance.” Chemical Physics Letters, vol. 331, no. 2-4, Dec. 2000, pp. 243-252. https://doi.org/10.1016/S0009-2614(00)01171-4.