Organic ferromagnetism of Tc=6.7 K driven by evaporation of crystal solvent
Wataru FUJITA
1
,
Kunio Awaga
2, 3, 4
2
Department of Chemistry, Graduate School of Science
4
Chikusa-ku Nagoya 464-8602 Japan
|
Publication type: Journal Article
Publication date: 2002-05-01
scimago Q2
wos Q2
SJR: 0.546
CiteScore: 5.9
Impact factor: 3.1
ISSN: 00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The crystals of the organic cation radical salt, BBDTA (benzo[1,2-d:4,5-d′]bis[1,3,2]dithiazole)·GaCl4·CH3CN, was found to consist of a ladder-type structure of BBDTA, coordinated by the crystal solvent, CH3CN. While this material exhibited diamagnetic properties, removal of the crystal solvent resulted in a drastic change from diamagnetic to paramagnetic, probably caused by a packing modification of the BBDTA molecules. The desolvated form made bulk, ferromagnetic ordering at 6.7 K. This finding has superseded the highest Curie temperature of organic ferromagnets based on ferromagnetic interactions,
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GOST
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FUJITA W. et al. Organic ferromagnetism of Tc=6.7 K driven by evaporation of crystal solvent // Chemical Physics Letters. 2002. Vol. 357. No. 5-6. pp. 385-388.
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FUJITA W., Awaga K. Organic ferromagnetism of Tc=6.7 K driven by evaporation of crystal solvent // Chemical Physics Letters. 2002. Vol. 357. No. 5-6. pp. 385-388.
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TY - JOUR
DO - 10.1016/S0009-2614(02)00535-3
UR - https://doi.org/10.1016/S0009-2614(02)00535-3
TI - Organic ferromagnetism of Tc=6.7 K driven by evaporation of crystal solvent
T2 - Chemical Physics Letters
AU - FUJITA, Wataru
AU - Awaga, Kunio
PY - 2002
DA - 2002/05/01
PB - Elsevier
SP - 385-388
IS - 5-6
VL - 357
SN - 0009-2614
SN - 1873-4448
ER -
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BibTex (up to 50 authors)
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@article{2002_FUJITA,
author = {Wataru FUJITA and Kunio Awaga},
title = {Organic ferromagnetism of Tc=6.7 K driven by evaporation of crystal solvent},
journal = {Chemical Physics Letters},
year = {2002},
volume = {357},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/S0009-2614(02)00535-3},
number = {5-6},
pages = {385--388},
doi = {10.1016/S0009-2614(02)00535-3}
}
Cite this
MLA
Copy
FUJITA, Wataru, et al. “Organic ferromagnetism of Tc=6.7 K driven by evaporation of crystal solvent.” Chemical Physics Letters, vol. 357, no. 5-6, May. 2002, pp. 385-388. https://doi.org/10.1016/S0009-2614(02)00535-3.
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