A new route to sulfur polyimido anions S(NR)nm−: reactivity and coordination behavior
Publication type: Journal Article
Publication date: 1998-09-01
scimago Q1
wos Q1
SJR: 4.638
CiteScore: 38.2
Impact factor: 23.5
ISSN: 00108545, 18733840
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
In a reaction sequence of amide addition followed by halogen oxidation the triazasulfite S(NR)32− and the tetrazasulfate S(NR)42− are readily accessible from sulfur diimide S(NR)2 via sulfur triimide S(NR)3. Addition of lithium organics to sulfur triimide provides a general route to triazasulfonates RS(NR)3−. All these anions resemble potential tripodal coordination behavior because of their nitrogen donor centers. Furthermore, the sulfur polyimido ligands are capable of responding to the various requirements of different metals (even in mixed metal species) by charge (de)localization. This review deals with the synthetic routes to the sulfur nitrogen anions and with their coordination behavior. The reactivity mainly towards main group metal synthons is discussed.
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GOST
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Fleischer R., Stalke D. A new route to sulfur polyimido anions S(NR)nm−: reactivity and coordination behavior // Coordination Chemistry Reviews. 1998. Vol. 176. No. 1. pp. 431-450.
GOST all authors (up to 50)
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Fleischer R., Stalke D. A new route to sulfur polyimido anions S(NR)nm−: reactivity and coordination behavior // Coordination Chemistry Reviews. 1998. Vol. 176. No. 1. pp. 431-450.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0010-8545(98)00130-1
UR - https://doi.org/10.1016/S0010-8545(98)00130-1
TI - A new route to sulfur polyimido anions S(NR)nm−: reactivity and coordination behavior
T2 - Coordination Chemistry Reviews
AU - Fleischer, Roland
AU - Stalke, Dietmar
PY - 1998
DA - 1998/09/01
PB - Elsevier
SP - 431-450
IS - 1
VL - 176
SN - 0010-8545
SN - 1873-3840
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1998_Fleischer,
author = {Roland Fleischer and Dietmar Stalke},
title = {A new route to sulfur polyimido anions S(NR)nm−: reactivity and coordination behavior},
journal = {Coordination Chemistry Reviews},
year = {1998},
volume = {176},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/S0010-8545(98)00130-1},
number = {1},
pages = {431--450},
doi = {10.1016/S0010-8545(98)00130-1}
}
Cite this
MLA
Copy
Fleischer, Roland, et al. “A new route to sulfur polyimido anions S(NR)nm−: reactivity and coordination behavior.” Coordination Chemistry Reviews, vol. 176, no. 1, Sep. 1998, pp. 431-450. https://doi.org/10.1016/S0010-8545(98)00130-1.