Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3 )(μ-S-SCMe3 )Cr(NO)Cp and monomer CpCr(NO)2 (ONO)
Publication type: Journal Article
Publication date: 1981-01-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Reaction of CpCp (I) with NO in THF led to the binuclear complex Cp(NO)(NO)Cp (II) and monomer CpCr(NO)2(ONO) (III). The X-ray study demonstrates that the complex II has an ordinary CrCr bond (2.906(3) A) supported by the bridged SCMe3 (CrS 2.295(4) A) and (SSCMe3 (CrS 2.296(4) A), (SS 2.076(4) A) groups. In the monomeric complex III the Cr atom is surrounded by π-C5H5 (CrC 2.24(3) A), two terminal NO groups (CrN 1.71(1) A) and terminal ONO group (CrO 1.982(4) A, ONO 115(2)°).
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Total citations:
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Citations from 2024:
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Eremenko I. L. et al. Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO) // Inorganica Chimica Acta. 1981. Vol. 52. No. C. pp. 107-111.
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Eremenko I. L., Pasynskii A. A., Kalinnikov V. Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO) // Inorganica Chimica Acta. 1981. Vol. 52. No. C. pp. 107-111.
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TY - JOUR
DO - 10.1016/S0020-1693(00)88582-5
UR - https://doi.org/10.1016/S0020-1693(00)88582-5
TI - Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO)
T2 - Inorganica Chimica Acta
AU - Eremenko, Igor L.
AU - Pasynskii, A. A.
AU - Kalinnikov, V.T
PY - 1981
DA - 1981/01/01
PB - Elsevier
SP - 107-111
IS - C
VL - 52
SN - 0020-1693
SN - 1873-3255
ER -
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BibTex (up to 50 authors)
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@article{1981_Eremenko,
author = {Igor L. Eremenko and A. A. Pasynskii and V.T Kalinnikov},
title = {Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO)},
journal = {Inorganica Chimica Acta},
year = {1981},
volume = {52},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0020-1693(00)88582-5},
number = {C},
pages = {107--111},
doi = {10.1016/S0020-1693(00)88582-5}
}
Cite this
MLA
Copy
Eremenko, Igor L., et al. “Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO).” Inorganica Chimica Acta, vol. 52, no. C, Jan. 1981, pp. 107-111. https://doi.org/10.1016/S0020-1693(00)88582-5.
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