Inorganica Chimica Acta

, том 52 , издание C , страницы 107-111

Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO)

Тип публикации: Journal Article

Дата публикации: 1981-01-01

Elsevier

Inorganica Chimica Acta

SCImago Q2

WOS Q2

БС2

SJR: 0.425

CiteScore: 5.5

Impact factor: 3.2

ISSN: 00201693, 18733255

DOI: 10.1016/S0020-1693(00)88582-5

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

Reaction of CpCp (I) with NO in THF led to the binuclear complex Cp(NO)(NO)Cp (II) and monomer CpCr(NO)2(ONO) (III). The X-ray study demonstrates that the complex II has an ordinary CrCr bond (2.906(3) A) supported by the bridged SCMe3 (CrS 2.295(4) A) and (SSCMe3 (CrS 2.296(4) A), (SS 2.076(4) A) groups. In the monomeric complex III the Cr atom is surrounded by π-C5H5 (CrC 2.24(3) A), two terminal NO groups (CrN 1.71(1) A) and terminal ONO group (CrO 1.982(4) A, ONO 115(2)°).

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Eremenko I. L. et al. Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO) // Inorganica Chimica Acta. 1981. Vol. 52. No. C. pp. 107-111.

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Eremenko I. L., Pasynskii A. A., Kalinnikov V. Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO) // Inorganica Chimica Acta. 1981. Vol. 52. No. C. pp. 107-111.

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TY - JOUR

DO - 10.1016/S0020-1693(00)88582-5

UR - https://doi.org/10.1016/S0020-1693(00)88582-5

TI - Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO)

T2 - Inorganica Chimica Acta

AU - Eremenko, Igor L.

AU - Pasynskii, A. A.

AU - Kalinnikov, V.T

PY - 1981

DA - 1981/01/01

PB - Elsevier

SP - 107-111

IS - C

VL - 52

SN - 0020-1693

SN - 1873-3255

ER -

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@article{1981_Eremenko,

author = {Igor L. Eremenko and A. A. Pasynskii and V.T Kalinnikov},

title = {Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO)},

journal = {Inorganica Chimica Acta},

year = {1981},

volume = {52},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/S0020-1693(00)88582-5},

number = {C},

pages = {107--111},

doi = {10.1016/S0020-1693(00)88582-5}

}

MLA

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Eremenko, Igor L., et al. “Nitrosylation of dicyclopentadienyldi(μ-tert-butylthiolato)(μ-sulfido)dichromium giving tert-butylsulfanic group. Molecular structures of the binuclear complex Cp(NO)Cr(μ-SCMe3)(μ-S-SCMe3)Cr(NO)Cp and monomer CpCr(NO)2(ONO).” Inorganica Chimica Acta, vol. 52, no. C, Jan. 1981, pp. 107-111. https://doi.org/10.1016/S0020-1693(00)88582-5.

Издатель

Elsevier

Журнал

Inorganica Chimica Acta

SCImago Q2

WOS Q2

БС2

SJR

0.425

CiteScore

5.5

Impact factor