Elsevier
Inorganica Chimica Acta
,  volume 73 ,  issue C ,  pages 225-229

Interaction of Heteronuclear chromium-containing clusters with carboxalic acids. Molecular structure of the paramagnetic tetrahedral cluster Cp3Cr3(μ3-S)4Fe (OOCCMe3)

Publication type: Journal Article
Publication date: 1983-01-01
Elsevier
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of (CpCrSCMe3)2S and the adducts (CpCrSCMe3)2S·ML (ML = Cr(CO)5, Mn2(CO)9 and cluster (CpCrS)2(SCMe3)·Fe(CO)3 (I) (containing CrCrFe metal chain) with benzoic acid gives the respective antiferromagnetic μ3-thio-bridged carboxylates Cr2MS(OOCPh)6 (M = Cr(II), Mn(II), Fe(II)) (II–IV). On the other hand the reaction of I with the weaker trimethylacetic acid yields the tetrahedral cluster Cp3Cr3(μ3-S)4Fe(OOCCMe3) (V) containing two unpaired electrons (μeff = 2.81 BM). Crystal structure of V was solved by means of X-ray analysis (sp. gr. C2)c, a = 28.905(2), b = 9.563(2), c = 23.789(2) A, β = 131.84(3)°, V = 4902.8(4) A3 Z = 4). In the metal tetrahedral skeleton Cr3Fe the average bond lengths CrCr and FeCr are 2.838(3) and 2.759(3) A respectively. The μ3-bridged sulfur atom locates over each tetrahedron face (the average CrS and FeS distances are 2.258(4) and 2.218(4) A respectively). Each chromium atom is combined to η5-C5H5 ligand (the average CrC and CC distances are 2.224(20) and 1.391(30) A). The iron atom is bound to a terminal trimethylacetate group (FeO 1.896(10), O(1)C(1) 1.318(13), O(2)C(1) 1.252(21) A).
Found 
Found 

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Eremenko I. L. et al. Interaction of Heteronuclear chromium-containing clusters with carboxalic acids. Molecular structure of the paramagnetic tetrahedral cluster Cp3Cr3(μ3-S)4Fe (OOCCMe3) // Inorganica Chimica Acta. 1983. Vol. 73. No. C. pp. 225-229.
GOST all authors (up to 50) Copy
Eremenko I. L., Pasynskii A. A., Orazsakhatov B., Ellert O., Novotortsev V. M., Kalinnikov V., Porai-Koshits M. A., Antsyshkina A. S., Dikareva L. M., Ostrikova V. N., Struchkov Y. T., Gerr R. G. Interaction of Heteronuclear chromium-containing clusters with carboxalic acids. Molecular structure of the paramagnetic tetrahedral cluster Cp3Cr3(μ3-S)4Fe (OOCCMe3) // Inorganica Chimica Acta. 1983. Vol. 73. No. C. pp. 225-229.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/S0020-1693(00)90855-7
UR - https://doi.org/10.1016/S0020-1693(00)90855-7
TI - Interaction of Heteronuclear chromium-containing clusters with carboxalic acids. Molecular structure of the paramagnetic tetrahedral cluster Cp3Cr3(μ3-S)4Fe (OOCCMe3)
T2 - Inorganica Chimica Acta
AU - Eremenko, Igor L.
AU - Pasynskii, A. A.
AU - Orazsakhatov, B
AU - Ellert, O.G
AU - Novotortsev, V. M.
AU - Kalinnikov, V.T
AU - Porai-Koshits, M. A.
AU - Antsyshkina, A S
AU - Dikareva, L M
AU - Ostrikova, V N
AU - Struchkov, Yu. T.
AU - Gerr, R. G.
PY - 1983
DA - 1983/01/01
PB - Elsevier
SP - 225-229
IS - C
VL - 73
SN - 0020-1693
SN - 1873-3255
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{1983_Eremenko,
author = {Igor L. Eremenko and A. A. Pasynskii and B Orazsakhatov and O.G Ellert and V. M. Novotortsev and V.T Kalinnikov and M. A. Porai-Koshits and A S Antsyshkina and L M Dikareva and V N Ostrikova and Yu. T. Struchkov and R. G. Gerr},
title = {Interaction of Heteronuclear chromium-containing clusters with carboxalic acids. Molecular structure of the paramagnetic tetrahedral cluster Cp3Cr3(μ3-S)4Fe (OOCCMe3)},
journal = {Inorganica Chimica Acta},
year = {1983},
volume = {73},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0020-1693(00)90855-7},
number = {C},
pages = {225--229},
doi = {10.1016/S0020-1693(00)90855-7}
}
MLA
Cite this
MLA Copy
Eremenko, Igor L., et al. “Interaction of Heteronuclear chromium-containing clusters with carboxalic acids. Molecular structure of the paramagnetic tetrahedral cluster Cp3Cr3(μ3-S)4Fe (OOCCMe3).” Inorganica Chimica Acta, vol. 73, no. C, Jan. 1983, pp. 225-229. https://doi.org/10.1016/S0020-1693(00)90855-7.