Nano-sized octa-nuclear nickel cationic complex: Self-assembly on supramolecular level
Igor L. Eremenko
1
,
Aleksei E. Malkov
1
,
Grygory G. Aleksandrov
1
,
Sergei E Nefedov
1
,
Irina G. Fomina
1
,
Gennady L. Rusinov
2
,
Vladimir M. Novotortsev
1
,
Vladimir N Ikorskii
3
,
O. N. Chupakhin
2
,
Publication type: Journal Article
Publication date: 2002-05-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Microporous one-dimensional material was synthesized by reacting Ni-9 cluster compound Ni9(HOOCCMe3)4(μ4-OH)3(μ3-OH)3(OOCCMe3)12 with organic ligand 3-(3,5-dimethylpyrazol-1-yl)-6-(3,5-diamino-1,3,4-thiadiazolyl)-1,2,4,5-tetrazine) (L). According to X-ray data, the nano-sized endless tubes of the material consist of stacked cationic Ni(II) octa-nuclear cyclic complexes of formula [Ni8(μ-OH2)4(μ-OOCCMe3)4(η2-OOCCMe3)(OOCCMe3)10L4]+ and pivalate anions ordered regularly aside the tubes. The channels of the tubes are filled with acetonitrile molecules forming an inclusion compound.
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Malkov A. E. et al. Nano-sized octa-nuclear nickel cationic complex: Self-assembly on supramolecular level // Inorganica Chimica Acta. 2002. Vol. 334. pp. 334-342.
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Eremenko I. L., Malkov A. E., Sidorov A. A., Aleksandrov G. G., Nefedov S. E., Fomina I. G., Rusinov G. L., Novotortsev V. M., Ikorskii V. N., Chupakhin O. N., Moiseev I. I. Nano-sized octa-nuclear nickel cationic complex: Self-assembly on supramolecular level // Inorganica Chimica Acta. 2002. Vol. 334. pp. 334-342.
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TY - JOUR
DO - 10.1016/S0020-1693(02)00856-3
UR - https://doi.org/10.1016/S0020-1693(02)00856-3
TI - Nano-sized octa-nuclear nickel cationic complex: Self-assembly on supramolecular level
T2 - Inorganica Chimica Acta
AU - Eremenko, Igor L.
AU - Malkov, Aleksei E.
AU - Sidorov, Aleksei A.
AU - Aleksandrov, Grygory G.
AU - Nefedov, Sergei E
AU - Fomina, Irina G.
AU - Rusinov, Gennady L.
AU - Novotortsev, Vladimir M.
AU - Ikorskii, Vladimir N
AU - Chupakhin, O. N.
AU - Moiseev, I. I.
PY - 2002
DA - 2002/05/01
PB - Elsevier
SP - 334-342
VL - 334
SN - 0020-1693
SN - 1873-3255
ER -
Cite this
BibTex (up to 50 authors)
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@article{2002_Malkov,
author = {Igor L. Eremenko and Aleksei E. Malkov and Aleksei A. Sidorov and Grygory G. Aleksandrov and Sergei E Nefedov and Irina G. Fomina and Gennady L. Rusinov and Vladimir M. Novotortsev and Vladimir N Ikorskii and O. N. Chupakhin and I. I. Moiseev},
title = {Nano-sized octa-nuclear nickel cationic complex: Self-assembly on supramolecular level},
journal = {Inorganica Chimica Acta},
year = {2002},
volume = {334},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/S0020-1693(02)00856-3},
pages = {334--342},
doi = {10.1016/S0020-1693(02)00856-3}
}