Inorganica Chimica Acta, volume 186, issue 1, pages 51-60
Crystal structures of three basic zinc carboxylates together with infrared and FAB mass spectrometry studies in solution
Publication type: Journal Article
Publication date: 1991-08-01
Journal:
Inorganica Chimica Acta
Q2
Q2
SJR: 0.386
CiteScore: 6.0
Impact factor: 2.7
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
We report the X-ray crystal structures of three new basic zinc carboxylate complexes, [Zn4O(O2CR)6] where RC(CH3)3 (pivalate) or C6H5 (benzoate) and [Zn5(OH)2(O2CCHCHCH3)8]x (crotonate). The basic pivalate is orthorhombic, Cmc21, with a=18.609(1), b=11.027(1), c=22.439(1)A, Z=4; R=0.042 for 1887 unique observed reflections. The basic benzoate is monoclinic, P21/m, with a=10.818(2), b=18.527(3), c=12.170(2) A, β=110.32(1)°, Z=2; R=0.036 for 3633 unique observed reflections. The basic crotonate is monoclinic, P21/n, with a=8.723(1), b=21.957(2), c=11.302(1) A, β=90.94(1)°, Z=2; R=0.058 for 3049 unique observed reflections. The pivalate and benzoate structures possess the well-known tetranuclear structure containing a central oxygen atom, while the structure of the crotonate complex consists of a chain polymer. In solutions containing traces of water, the hydrated basic structures appear to be in equilibrium with hydrated forms of the normal 3,1 metal carboxylate structures reported previously and their interconversions have been investigated using FTIR and FAB mass spectral data.
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Clegg W. et al. Crystal structures of three basic zinc carboxylates together with infrared and FAB mass spectrometry studies in solution // Inorganica Chimica Acta. 1991. Vol. 186. No. 1. pp. 51-60.
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Clegg W., Harbron D. R., Homan C. M., Hunt P. A., Little I. R., Straughan B. Crystal structures of three basic zinc carboxylates together with infrared and FAB mass spectrometry studies in solution // Inorganica Chimica Acta. 1991. Vol. 186. No. 1. pp. 51-60.
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TY - JOUR
DO - 10.1016/S0020-1693(00)87930-X
UR - https://doi.org/10.1016/S0020-1693(00)87930-X
TI - Crystal structures of three basic zinc carboxylates together with infrared and FAB mass spectrometry studies in solution
T2 - Inorganica Chimica Acta
AU - Clegg, William
AU - Harbron, Dale R
AU - Homan, Christopher M.
AU - Hunt, Paul A
AU - Little, Ian R
AU - Straughan, Brian
PY - 1991
DA - 1991/08/01
PB - Elsevier
SP - 51-60
IS - 1
VL - 186
SN - 0020-1693
SN - 1873-3255
ER -
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@article{1991_Clegg,
author = {William Clegg and Dale R Harbron and Christopher M. Homan and Paul A Hunt and Ian R Little and Brian Straughan},
title = {Crystal structures of three basic zinc carboxylates together with infrared and FAB mass spectrometry studies in solution},
journal = {Inorganica Chimica Acta},
year = {1991},
volume = {186},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/S0020-1693(00)87930-X},
number = {1},
pages = {51--60},
doi = {10.1016/S0020-1693(00)87930-X}
}
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MLA
Copy
Clegg, William, et al. “Crystal structures of three basic zinc carboxylates together with infrared and FAB mass spectrometry studies in solution.” Inorganica Chimica Acta, vol. 186, no. 1, Aug. 1991, pp. 51-60. https://doi.org/10.1016/S0020-1693(00)87930-X.