Inorganica Chimica Acta

, volume 286 , issue 1 , pages 93-97

NMR investigation of Pd(II)–Pd(0) reduction in the presence of mono- and ditertiary phosphines

Zita Csákai ¹

R. Skoda-Földes ¹

László Kollár ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Organic Chemistry, University of Veszprém, P.O. Box 158, H-8201 Veszprém, Hungary |

Publication type: Journal Article

Publication date: 1999-03-01

Elsevier

Inorganica Chimica Acta

scimago Q3

wos Q2

SJR: 0.393

CiteScore: 5.5

Impact factor: 3.2

ISSN: 00201693, 18733255

DOI: 10.1016/S0020-1693(98)00366-1

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

The reduction of Pd(II) to Pd(0) was investigated in the presence of both monodentate (PPh3) and bidentate (dppp=1,3-bis(diphenylphosphino)propane) phosphines. It was shown by 31P NMR measurements that triphenylphosphine can reduce Pd(OAc)2 to zerovalent palladium in toluene and dppp is mainly responsible for the reduction in dmf resulting in dppp hemioxide and dppp dioxide. Both mono- and bidentate coordinations of dppp in intermediate species are proposed on the basis of in situ NMR studies. In the presence of two equivalents of silver triflate, the formation of the [Pd(dppp)(PPh3)2]2+ square-planar complex cation has been observed without any reduction of Pd(II) to Pd(0) species.

Found

1 citation

Davydova Maria

PhD in Chemistry

42 publications, 816 citations

h-index: 16

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Research interests

Circularly polarized luminescence

Clusters

Coordination chemistry

Coordination polymers

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GOST |

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GOST Copy

Csákai Z. et al. NMR investigation of Pd(II)–Pd(0) reduction in the presence of mono- and ditertiary phosphines // Inorganica Chimica Acta. 1999. Vol. 286. No. 1. pp. 93-97.

GOST all authors (up to 50) Copy

Csákai Z., Skoda-Földes R., Kollár L. NMR investigation of Pd(II)–Pd(0) reduction in the presence of mono- and ditertiary phosphines // Inorganica Chimica Acta. 1999. Vol. 286. No. 1. pp. 93-97.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/S0020-1693(98)00366-1

UR - https://doi.org/10.1016/S0020-1693(98)00366-1

TI - NMR investigation of Pd(II)–Pd(0) reduction in the presence of mono- and ditertiary phosphines

T2 - Inorganica Chimica Acta

AU - Csákai, Zita

AU - Skoda-Földes, R.

AU - Kollár, László

PY - 1999

DA - 1999/03/01

PB - Elsevier

SP - 93-97

IS - 1

VL - 286

SN - 0020-1693

SN - 1873-3255

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{1999_Csákai,

author = {Zita Csákai and R. Skoda-Földes and László Kollár},

title = {NMR investigation of Pd(II)–Pd(0) reduction in the presence of mono- and ditertiary phosphines},

journal = {Inorganica Chimica Acta},

year = {1999},

volume = {286},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/S0020-1693(98)00366-1},

number = {1},

pages = {93--97},

doi = {10.1016/S0020-1693(98)00366-1}

}

MLA

Cite this

MLA Copy

Csákai, Zita, et al. “NMR investigation of Pd(II)–Pd(0) reduction in the presence of mono- and ditertiary phosphines.” Inorganica Chimica Acta, vol. 286, no. 1, Mar. 1999, pp. 93-97. https://doi.org/10.1016/S0020-1693(98)00366-1.

Publisher

Elsevier

Journal

Inorganica Chimica Acta

scimago Q3

wos Q2

SJR

0.393

CiteScore

5.5

Impact factor

3.2

ISSN

00201693 (Print)

18733255 (Electronic)