Transition metal-catalyzed borylation of alkanes and arenes via CH activation
Publication type: Journal Article
Publication date: 2003-08-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Since 1999, direct borylation of hydrocarbons catalyzed by a transition metal complex has been extensively studied by several groups and has become an economical, efficient, elegant, and environmentally benign protocol for the synthesis of a variety of organoboron compounds. Re-, Rh-, Ir- and Pd-catalyzed CH borylation of alkanes, arenes and benzylic positions of alkylarenes by bis(pinacolato)diboron or pinacolborane provide alkyl-, aryl-, heteroaryl- and benzylboron compounds, respectively. In this review, seminal early works and exciting recent developments in the area of direct borylation of hydrocarbons via CH activation are summarized. This review describes seminal early works and exciting recent developments of transition metal-catalyzed CH borylation. Re-, Rh-, Ir- and Pd- catalyzed reactions of alkanes, arenes and benezylic positions of alkylarenes with bis(pinacolato)diboron or pinacolborane provide alkyl-, aryl-, heteroaryl- and benzylboronates, respectively.
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Total citations:
306
Citations from 2024:
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GOST
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Ishiyama T., Miyaura N. Transition metal-catalyzed borylation of alkanes and arenes via CH activation // Journal of Organometallic Chemistry. 2003. Vol. 680. No. 1-2. pp. 3-11.
GOST all authors (up to 50)
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Ishiyama T., Miyaura N. Transition metal-catalyzed borylation of alkanes and arenes via CH activation // Journal of Organometallic Chemistry. 2003. Vol. 680. No. 1-2. pp. 3-11.
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TY - JOUR
DO - 10.1016/S0022-328X(03)00176-1
UR - https://doi.org/10.1016/S0022-328X(03)00176-1
TI - Transition metal-catalyzed borylation of alkanes and arenes via CH activation
T2 - Journal of Organometallic Chemistry
AU - Ishiyama, Tatsuo
AU - Miyaura, Norio
PY - 2003
DA - 2003/08/01
PB - Elsevier
SP - 3-11
IS - 1-2
VL - 680
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2003_Ishiyama,
author = {Tatsuo Ishiyama and Norio Miyaura},
title = {Transition metal-catalyzed borylation of alkanes and arenes via CH activation},
journal = {Journal of Organometallic Chemistry},
year = {2003},
volume = {680},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/S0022-328X(03)00176-1},
number = {1-2},
pages = {3--11},
doi = {10.1016/S0022-328X(03)00176-1}
}
Cite this
MLA
Copy
Ishiyama, Tatsuo, and Norio Miyaura. “Transition metal-catalyzed borylation of alkanes and arenes via CH activation.” Journal of Organometallic Chemistry, vol. 680, no. 1-2, Aug. 2003, pp. 3-11. https://doi.org/10.1016/S0022-328X(03)00176-1.