Antiferromagnetic complexes with metal—metal bonds
A. A. Pasynskii
1
,
Igor L. Eremenko
1
,
B Orazsakhatov
1
,
V.T Kalinnikov
1
,
G.G. Aleksandrov
2
,
Yu. T. Struchkov
2
Publication type: Journal Article
Publication date: 1981-07-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Summary Heating the antiferromagnetic metallacycle (CpCr(SCMe 3 )CrCp)·(μ 3 −S) 2 (CO) 2 (I) in toluene in the presence of diphenylacetylene yields the diamagnetic tetrahedral cluster Cp 3 Cr 3 (μ 3 −S) 2 ·Co(CO) (II). Its X-ray analysis shows that the tetrahedron has a Cp 3 Cr 3 triangle (mean Cr−Cr length is 2.818(4) A) at the base and a Co(CO) group at the vertex (mean Co−Cr length is 2.658(4) A). Each of the four S atoms is located on a tetrahedron face producing a pseudo-cubanic structure of Co and Cr atoms (Co−S mean length 2.163(6) A and Cr−S mean length 2.244(6) A).
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Total citations:
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Citations from 2024:
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GOST
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Pasynskii A. A. et al. Antiferromagnetic complexes with metal—metal bonds // Journal of Organometallic Chemistry. 1981. Vol. 214. No. 3. pp. 367-372.
GOST all authors (up to 50)
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Pasynskii A. A., Eremenko I. L., Orazsakhatov B., Kalinnikov V., Aleksandrov G., Struchkov Y. T. Antiferromagnetic complexes with metal—metal bonds // Journal of Organometallic Chemistry. 1981. Vol. 214. No. 3. pp. 367-372.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0022-328X(81)80010-1
UR - https://doi.org/10.1016/S0022-328X(81)80010-1
TI - Antiferromagnetic complexes with metal—metal bonds
T2 - Journal of Organometallic Chemistry
AU - Pasynskii, A. A.
AU - Eremenko, Igor L.
AU - Orazsakhatov, B
AU - Kalinnikov, V.T
AU - Aleksandrov, G.G.
AU - Struchkov, Yu. T.
PY - 1981
DA - 1981/07/01
PB - Elsevier
SP - 367-372
IS - 3
VL - 214
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{1981_Pasynskii,
author = {A. A. Pasynskii and Igor L. Eremenko and B Orazsakhatov and V.T Kalinnikov and G.G. Aleksandrov and Yu. T. Struchkov},
title = {Antiferromagnetic complexes with metal—metal bonds},
journal = {Journal of Organometallic Chemistry},
year = {1981},
volume = {214},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/S0022-328X(81)80010-1},
number = {3},
pages = {367--372},
doi = {10.1016/S0022-328X(81)80010-1}
}
Cite this
MLA
Copy
Pasynskii, A. A., et al. “Antiferromagnetic complexes with metal—metal bonds.” Journal of Organometallic Chemistry, vol. 214, no. 3, Jul. 1981, pp. 367-372. https://doi.org/10.1016/S0022-328X(81)80010-1.
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