Weak interactions and tautomerism in 3,5-dinitrosubstituted 2- and 4-hydroxypyridines and products of their reaction with [O(AuPPh3 )3 ]BF4 : Synthesis, X-ray structure, IR and UV spectroscopy, and quantum chemical calculations
Lyudmilag Kuzmina
1
,
Juditha K Howard
2
,
Kirai Grandberg
3
,
Elenas Shubina
4
,
Liliyan Saitkulova
4
,
Ekaterinav Bakhmutova
4
,
A. A. Bagatur'yants
5
,
Alexander V Karchava
3
Publication type: Journal Article
Publication date: 1999-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Products of the interaction of 3,5-dinitrosubstituted ortho- and para- hydroxypyridines with [O(AuPPh 3 ) 3 ][BF 4 ] are investigated by X-ray crystallography, IR and UV spectroscopy. The structure of the parent organic molecules are investigated by the spectroscopic methods and ab initio quantum chemical calculations. The calculation and spectroscopy show that the corresponding organic molecules can exist in both tautomeric forms. The reaction with the ortho isomer results in the N-aurated dimer {[NC 5 H 2 (NO 2 ) 2 O](AuPPh 3 )} 2 bound through interaction. Under similar conditions, the para isomer yields a salt of composition [O(AuPPh 3 ) 3 ][NC 5 H 2 (NO 2 ) 2 O].
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Kuzmina L. et al. Weak interactions and tautomerism in 3,5-dinitrosubstituted 2- and 4-hydroxypyridines and products of their reaction with [O(AuPPh3)3]BF4: Synthesis, X-ray structure, IR and UV spectroscopy, and quantum chemical calculations // Journal of Organometallic Chemistry. 1999. Vol. 575. No. 1. pp. 39-50.
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Kuzmina L., Howard J. K., Grandberg K., Shubina E., Saitkulova L., Bakhmutova E., Bagatur'yants A. A., Karchava A. V. Weak interactions and tautomerism in 3,5-dinitrosubstituted 2- and 4-hydroxypyridines and products of their reaction with [O(AuPPh3)3]BF4: Synthesis, X-ray structure, IR and UV spectroscopy, and quantum chemical calculations // Journal of Organometallic Chemistry. 1999. Vol. 575. No. 1. pp. 39-50.
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TY - JOUR
DO - 10.1016/S0022-328X(98)00949-8
UR - https://doi.org/10.1016/S0022-328X(98)00949-8
TI - Weak interactions and tautomerism in 3,5-dinitrosubstituted 2- and 4-hydroxypyridines and products of their reaction with [O(AuPPh3)3]BF4: Synthesis, X-ray structure, IR and UV spectroscopy, and quantum chemical calculations
T2 - Journal of Organometallic Chemistry
AU - Kuzmina, Lyudmilag
AU - Howard, Juditha K
AU - Grandberg, Kirai
AU - Shubina, Elenas
AU - Saitkulova, Liliyan
AU - Bakhmutova, Ekaterinav
AU - Bagatur'yants, A. A.
AU - Karchava, Alexander V
PY - 1999
DA - 1999/02/01
PB - Elsevier
SP - 39-50
IS - 1
VL - 575
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1999_Kuzmina,
author = {Lyudmilag Kuzmina and Juditha K Howard and Kirai Grandberg and Elenas Shubina and Liliyan Saitkulova and Ekaterinav Bakhmutova and A. A. Bagatur'yants and Alexander V Karchava},
title = {Weak interactions and tautomerism in 3,5-dinitrosubstituted 2- and 4-hydroxypyridines and products of their reaction with [O(AuPPh3)3]BF4: Synthesis, X-ray structure, IR and UV spectroscopy, and quantum chemical calculations},
journal = {Journal of Organometallic Chemistry},
year = {1999},
volume = {575},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/S0022-328X(98)00949-8},
number = {1},
pages = {39--50},
doi = {10.1016/S0022-328X(98)00949-8}
}
Cite this
MLA
Copy
Kuzmina, Lyudmilag, et al. “Weak interactions and tautomerism in 3,5-dinitrosubstituted 2- and 4-hydroxypyridines and products of their reaction with [O(AuPPh3)3]BF4: Synthesis, X-ray structure, IR and UV spectroscopy, and quantum chemical calculations.” Journal of Organometallic Chemistry, vol. 575, no. 1, Feb. 1999, pp. 39-50. https://doi.org/10.1016/S0022-328X(98)00949-8.
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