Journal of Organometallic Chemistry

, том 587 , издание 1 , страницы 104-112

Neutral and cationic 1,4-diphospha-2-rhoda-3-thia-[4]-ferrocenophane

Тип публикации: Journal Article

Дата публикации: 1999-09-01

Elsevier

Journal of Organometallic Chemistry

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БС2

SJR: 0.385

CiteScore: 4.1

Impact factor: 2.4

ISSN: 0022328X, 18728561

DOI: 10.1016/S0022-328X(99)00293-4

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Materials Chemistry

Organic Chemistry

Biochemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

Abstract A mixed bidentate ferrocenyl ligand Fe(η5-C5Me4P(S)Ph2)(η5-C5Me4PPh2) (abbreviated {P,PS}) was synthesised and used for complexation with [RhCl(CO)2]2. The neutral [4]-ferrocenophane {P,PS}Rh(CO)Cl 2 and the unusual dimeric cationic species [{P,PS}Rh(CO)(μ-Cl)(CO)Rh{P,PS}]+ 3 were obtained and characterized by crystal structure analysis. During investigations on the catalytic properties of 2 in carbonylation, some aspects of its behavior towards iodomethane were elucidated.

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Broussier R. et al. Neutral and cationic 1,4-diphospha-2-rhoda-3-thia-[4]-ferrocenophane // Journal of Organometallic Chemistry. 1999. Vol. 587. No. 1. pp. 104-112.

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Broussier R., Laly M., Perron P., Gautheron B., Nifant'ev I. E., Howard J. A., Kuz'mina L. G., Kalck P. Neutral and cationic 1,4-diphospha-2-rhoda-3-thia-[4]-ferrocenophane // Journal of Organometallic Chemistry. 1999. Vol. 587. No. 1. pp. 104-112.

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TY - JOUR

DO - 10.1016/S0022-328X(99)00293-4

UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X99002934

TI - Neutral and cationic 1,4-diphospha-2-rhoda-3-thia-[4]-ferrocenophane

T2 - Journal of Organometallic Chemistry

AU - Broussier, Roland

AU - Laly, Myriam

AU - Perron, Patrice

AU - Gautheron, Bernard

AU - Nifant'ev, Ilya E.

AU - Howard, Judith A.

AU - Kuz'mina, Lyudmila G.

AU - Kalck, Philippe

PY - 1999

DA - 1999/09/01

PB - Elsevier

SP - 104-112

IS - 1

VL - 587

SN - 0022-328X

SN - 1872-8561

ER -

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@article{1999_Broussier,

author = {Roland Broussier and Myriam Laly and Patrice Perron and Bernard Gautheron and Ilya E. Nifant'ev and Judith A. Howard and Lyudmila G. Kuz'mina and Philippe Kalck},

title = {Neutral and cationic 1,4-diphospha-2-rhoda-3-thia-[4]-ferrocenophane},

journal = {Journal of Organometallic Chemistry},

year = {1999},

volume = {587},

publisher = {Elsevier},

month = {sep},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X99002934},

number = {1},

pages = {104--112},

doi = {10.1016/S0022-328X(99)00293-4}

}

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Broussier, Roland, et al. “Neutral and cationic 1,4-diphospha-2-rhoda-3-thia-[4]-ferrocenophane.” Journal of Organometallic Chemistry, vol. 587, no. 1, Sep. 1999, pp. 104-112. https://linkinghub.elsevier.com/retrieve/pii/S0022328X99002934.