Journal of Organometallic Chemistry, volume 606, issue 1, pages 65-74

Synthesis and reactivity of novel ruthenium carbene catalysts. X-ray structures of [RuCl2(CHSC6H5)(PiPr3)2] and [RuCl2(CHCH2CH2-C,N-2-C5H4N)(PiPr3)]

Paul A van der Schaaf ¹

Roman Kolly ¹

Hans-Jürg Kirner ¹

Francois Rime ¹

Andreas Muhlebach

Andreas Mühlebach ¹

Andreas Hafner ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Ciba Specialty Chemicals, CH‐4002 Basel (Switzerland) |

Publication type: Journal Article

Publication date: 2000-07-01

Elsevier

Journal: Journal of Organometallic Chemistry

Quartile SCImago

Quartile WOS

Impact factor: 2.3

ISSN: 0022328X

DOI: 10.1016/S0022-328X(00)00289-8

Copy DOI

Materials Chemistry

Organic Chemistry

Biochemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

Two novel classes of very air-stable ruthenium carbene complexes have been developed. The arylthio substituted ruthenium carbenes containing two bulky phosphines are deep purple solids, whereas the 2-pyridylethanyl substituted ruthenium carbene complexes contain only one bulky phosphine and are light-brown colored. One member of each class has been characterized with X-ray crystallography. The metathesis activity of these complexes has been investigated in the polymerization of dicyclopentadiene. Several excellent catalysts were identified. Desired geltimes and initiation temperatures could be easily tuned by changing the substitution pattern on the pendant ligand in the 2-pyridylethanyl substituted ruthenium carbenes.

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Journal of Molecular Catalysis A Chemical	Journal of Molecular Catalysis A Chemical, 2, 2.3% Journal of Molecular Catalysis A Chemical 2 publications, 2.3%
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Angewandte Chemie	Angewandte Chemie, 2, 2.3% Angewandte Chemie 2 publications, 2.3%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 2, 2.3% Angewandte Chemie - International Edition 2 publications, 2.3%
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Organic Letters	Organic Letters, 2, 2.3% Organic Letters 2 publications, 2.3%
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Journal of Organic Chemistry	Journal of Organic Chemistry, 1, 1.15% Journal of Organic Chemistry 1 publication, 1.15%
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Catalysts	Catalysts, 1, 1.15% Catalysts 1 publication, 1.15%
Progress in Polymer Science	Progress in Polymer Science, 1, 1.15% Progress in Polymer Science 1 publication, 1.15%
Catalysis Today	Catalysis Today, 1, 1.15% Catalysis Today 1 publication, 1.15%
European Journal of Organic Chemistry	European Journal of Organic Chemistry, 1, 1.15% European Journal of Organic Chemistry 1 publication, 1.15%
Advanced Synthesis and Catalysis	Advanced Synthesis and Catalysis, 1, 1.15% Advanced Synthesis and Catalysis 1 publication, 1.15%
ChemCatChem	ChemCatChem, 1, 1.15% ChemCatChem 1 publication, 1.15%
Macromolecular Rapid Communications	Macromolecular Rapid Communications, 1, 1.15% Macromolecular Rapid Communications 1 publication, 1.15%
Inorganic Chemistry	Inorganic Chemistry, 1, 1.15% Inorganic Chemistry 1 publication, 1.15%
Chemical Reviews	Chemical Reviews, 1, 1.15% Chemical Reviews 1 publication, 1.15%
ACS Catalysis	ACS Catalysis, 1, 1.15% ACS Catalysis 1 publication, 1.15%
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	2 4 6 8 10 12

Citations by publishers

	5 10 15 20 25 30
Wiley	Wiley, 26, 29.89% Wiley 26 publications, 29.89%
American Chemical Society (ACS)	American Chemical Society (ACS), 23, 26.44% American Chemical Society (ACS) 23 publications, 26.44%
Elsevier	Elsevier, 14, 16.09% Elsevier 14 publications, 16.09%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 7, 8.05% Royal Society of Chemistry (RSC) 7 publications, 8.05%
Springer Nature	Springer Nature, 4, 4.6% Springer Nature 4 publications, 4.6%
Beilstein-Institut	Beilstein-Institut, 3, 3.45% Beilstein-Institut 3 publications, 3.45%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 2.3% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 2.3%
Thieme	Thieme, 2, 2.3% Thieme 2 publications, 2.3%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.15% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.15%
	5 10 15 20 25 30

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van der Schaaf P. A. et al. Synthesis and reactivity of novel ruthenium carbene catalysts. X-ray structures of [RuCl2(CHSC6H5)(PiPr3)2] and [RuCl2(CHCH2CH2-C,N-2-C5H4N)(PiPr3)] // Journal of Organometallic Chemistry. 2000. Vol. 606. No. 1. pp. 65-74.

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van der Schaaf P. A., Kolly R., Kirner H., Rime F., Muhlebach A., Mühlebach A., Hafner A. Synthesis and reactivity of novel ruthenium carbene catalysts. X-ray structures of [RuCl2(CHSC6H5)(PiPr3)2] and [RuCl2(CHCH2CH2-C,N-2-C5H4N)(PiPr3)] // Journal of Organometallic Chemistry. 2000. Vol. 606. No. 1. pp. 65-74.

RIS |

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TY - JOUR

DO - 10.1016/S0022-328X(00)00289-8

UR - https://doi.org/10.1016/S0022-328X(00)00289-8

TI - Synthesis and reactivity of novel ruthenium carbene catalysts. X-ray structures of [RuCl2(CHSC6H5)(PiPr3)2] and [RuCl2(CHCH2CH2-C,N-2-C5H4N)(PiPr3)]

T2 - Journal of Organometallic Chemistry

AU - van der Schaaf, Paul A

AU - Kolly, Roman

AU - Kirner, Hans-Jürg

AU - Rime, Francois

AU - Muhlebach, Andreas

AU - Mühlebach, Andreas

AU - Hafner, Andreas

PY - 2000

DA - 2000/07/01 00:00:00

PB - Elsevier

SP - 65-74

IS - 1

VL - 606

SN - 0022-328X

ER -

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@article{2000_van der Schaaf,

author = {Paul A van der Schaaf and Roman Kolly and Hans-Jürg Kirner and Francois Rime and Andreas Muhlebach and Andreas Mühlebach and Andreas Hafner},

title = {Synthesis and reactivity of novel ruthenium carbene catalysts. X-ray structures of [RuCl2(CHSC6H5)(PiPr3)2] and [RuCl2(CHCH2CH2-C,N-2-C5H4N)(PiPr3)]},

journal = {Journal of Organometallic Chemistry},

year = {2000},

volume = {606},

publisher = {Elsevier},

month = {jul},

url = {https://doi.org/10.1016/S0022-328X(00)00289-8},

number = {1},

pages = {65--74},

doi = {10.1016/S0022-328X(00)00289-8}

}

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MLA Copy

van der Schaaf, Paul A., et al. “Synthesis and reactivity of novel ruthenium carbene catalysts. X-ray structures of [RuCl2(CHSC6H5)(PiPr3)2] and [RuCl2(CHCH2CH2-C,N-2-C5H4N)(PiPr3)].” Journal of Organometallic Chemistry, vol. 606, no. 1, Jul. 2000, pp. 65-74. https://doi.org/10.1016/S0022-328X(00)00289-8.

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Publisher

Elsevier

Journal

Journal of Organometallic Chemistry

Quartile SCImago

Quartile WOS

Impact factor

2.3

ISSN

0022328X (Print)