Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes
Publication type: Journal Article
Publication date: 1978-08-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
An organometallic complex obtained by mixing Me 3 Al and Cl 2 TiCp 2 reacts with acetylenes to form monocarbometallated products in favorable cases, while dehydrometallation and polymerization compete in the cases of dialkylacetylenes having propargylic hydrogens and terminal acetylenes, respectively.
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52
Total citations:
52
Citations from 2024:
2
(3.85%)
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MLA
Cite this
GOST
Copy
Van Horn D. E. et al. Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes // Journal of Organometallic Chemistry. 1978. Vol. 156. No. 1. p. C20-C24.
GOST all authors (up to 50)
Copy
Van Horn D. E., Valente L. F., Idacavage M. J., Negishi E. Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes // Journal of Organometallic Chemistry. 1978. Vol. 156. No. 1. p. C20-C24.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0022-328X(00)84891-3
UR - https://doi.org/10.1016/S0022-328X(00)84891-3
TI - Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes
T2 - Journal of Organometallic Chemistry
AU - Van Horn, David E
AU - Valente, Louis F
AU - Idacavage, Michael J
AU - Negishi, Ei-ichi
PY - 1978
DA - 1978/08/01
PB - Elsevier
SP - C20-C24
IS - 1
VL - 156
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1978_Van Horn,
author = {David E Van Horn and Louis F Valente and Michael J Idacavage and Ei-ichi Negishi},
title = {Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes},
journal = {Journal of Organometallic Chemistry},
year = {1978},
volume = {156},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/S0022-328X(00)84891-3},
number = {1},
pages = {C20--C24},
doi = {10.1016/S0022-328X(00)84891-3}
}
Cite this
MLA
Copy
Van Horn, David E., et al. “Controlled carbometallation : II. The addition reaction of trimethylalane-titanocene dichloride with acetylenes.” Journal of Organometallic Chemistry, vol. 156, no. 1, Aug. 1978, pp. C20-C24. https://doi.org/10.1016/S0022-328X(00)84891-3.