Silver(I) trifluoromethanesulfonate π-complexes of olefins and alkynes. Stability and structure
1
Department of Chemistry, Sul Ross State University, Alpine, Texas 79830 U.S.A.
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Publication type: Journal Article
Publication date: 1976-10-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The decrease in chemical shift of the vinylic protons of cyclohexene with increasing silver(I) salt concentration indicates that extent of olefin π-complexation to silver salt decreases in the order silver trifluoromethanesulfonate > silver hexafluoroantimonate > silver tetrafluoroborate. Proton NMR analysis shows that alkynes π-complex nearly as well as olefins to silver trifluoromethanesulfonate. Silver trifluoromethanesulfonate π-complexes of monoenes, dienes, trienes, monoynes, and diynes have been prepared and isolated. All complexes are 1 : 1 in the solid state and solution, and all carbon—carbon multiple bonds are coordinated to silver ion. Stability constants measured by proton NMR for the alkyne—silver trifluoromethanesulfonate complexes decrease in the order 1,8-cyclotetradecadiyne > 3-hexyne > 2-hexyne > 4-methyl-2-pentyne.
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Total citations:
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Citations from 2025:
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(7.89%)
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GOST
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Lewandos G. S., Gregston D. K., Nelson F. R. Silver(I) trifluoromethanesulfonate π-complexes of olefins and alkynes. Stability and structure // Journal of Organometallic Chemistry. 1976. Vol. 118. No. 3. pp. 363-374.
GOST all authors (up to 50)
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Lewandos G. S., Gregston D. K., Nelson F. R. Silver(I) trifluoromethanesulfonate π-complexes of olefins and alkynes. Stability and structure // Journal of Organometallic Chemistry. 1976. Vol. 118. No. 3. pp. 363-374.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0022-328X(00)93217-0
UR - https://doi.org/10.1016/S0022-328X(00)93217-0
TI - Silver(I) trifluoromethanesulfonate π-complexes of olefins and alkynes. Stability and structure
T2 - Journal of Organometallic Chemistry
AU - Lewandos, Glenn S
AU - Gregston, Diana K
AU - Nelson, Frank R
PY - 1976
DA - 1976/10/01
PB - Elsevier
SP - 363-374
IS - 3
VL - 118
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1976_Lewandos,
author = {Glenn S Lewandos and Diana K Gregston and Frank R Nelson},
title = {Silver(I) trifluoromethanesulfonate π-complexes of olefins and alkynes. Stability and structure},
journal = {Journal of Organometallic Chemistry},
year = {1976},
volume = {118},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/S0022-328X(00)93217-0},
number = {3},
pages = {363--374},
doi = {10.1016/S0022-328X(00)93217-0}
}
Cite this
MLA
Copy
Lewandos, Glenn S., et al. “Silver(I) trifluoromethanesulfonate π-complexes of olefins and alkynes. Stability and structure.” Journal of Organometallic Chemistry, vol. 118, no. 3, Oct. 1976, pp. 363-374. https://doi.org/10.1016/S0022-328X(00)93217-0.