Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4
Publication type: Journal Article
Publication date: 2003-08-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The bright red title compound 1 was synthesized from (2-lithiophenyl)diphenylamine and bis(pentafluorophenyl)boron chloride. Its reactions with small acids like H2O and HCl proceeded easily giving zwitterionic compounds. For 1 and its water adduct 2 the crystal structures were determined, the latter featuring an ammonium borate structure containing a short intramolecular hydrogen bond bridge. Treatment of 1 with Jutzi's acid, [H(OEt2)2][B(C6F5)4], did not result in protonation of the nitrogen, but reaction of 1 with LiH in the presence of 12-crown-4, led to the isolation of the aminoborate [1-(Ph2N)-2-{B(H)(C6F5)2}C6H4][Li(12-crown-4)] (3). Borohydride 3 reacted with Jutzi's acid to regenerate 1 and liberate hydrogen.
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101
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GOST
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Roesler R., Piers W. E., Parvez M. Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4 // Journal of Organometallic Chemistry. 2003. Vol. 680. No. 1-2. pp. 218-222.
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Roesler R., Piers W. E., Parvez M. Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4 // Journal of Organometallic Chemistry. 2003. Vol. 680. No. 1-2. pp. 218-222.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0022-328X(03)00384-X
UR - https://doi.org/10.1016/S0022-328X(03)00384-X
TI - Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4
T2 - Journal of Organometallic Chemistry
AU - Roesler, Roland
AU - Piers, Warren E.
AU - Parvez, Masood
PY - 2003
DA - 2003/08/01
PB - Elsevier
SP - 218-222
IS - 1-2
VL - 680
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Roesler,
author = {Roland Roesler and Warren E. Piers and Masood Parvez},
title = {Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4},
journal = {Journal of Organometallic Chemistry},
year = {2003},
volume = {680},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/S0022-328X(03)00384-X},
number = {1-2},
pages = {218--222},
doi = {10.1016/S0022-328X(03)00384-X}
}
Cite this
MLA
Copy
Roesler, Roland, et al. “Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5)2]C6H4.” Journal of Organometallic Chemistry, vol. 680, no. 1-2, Aug. 2003, pp. 218-222. https://doi.org/10.1016/S0022-328X(03)00384-X.