Polymer

, volume 41 , issue 2 , pages 445-452

Exploring chromophore tethered aminoethers as potential photoinitiators for controlled radical polymerization

S. Hu ¹

J H Malpert ¹

X. Yang ¹

D. C. Neckers ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Center for Photochemical Sciences11Contribution No. 365 from the Center for Photochemical Sciences., Bowling Green State University, Bowling Green, OH 43403-0213, USA |

Publication type: Journal Article

Publication date: 2000-01-01

Elsevier

Polymer

scimago Q1

wos Q2

SJR: 0.843

CiteScore: 7.7

Impact factor: 4.5

ISSN: 00323861, 18732291

DOI: 10.1016/S0032-3861(99)00188-3

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Materials Chemistry

Organic Chemistry

Polymers and Plastics

Abstract

Compounds 1–4 containing various light absorbing chromophores attached covalently to a hindered aminoether (2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) aminoether) were synthesized, and their photochemistry and photophysics studied in an attempt to develop photoinitiators for radical “living” polymerization. Significant shortening of the chromophore's triplet lifetime was observed in 1–4 as compared to analogous compounds containing no alkylated TEMPO moiety, which suggests an intramolecular quenching of the excited chromophore by the aminoether functionality. The efficiency of the quenching process depends on the chromophore. Employing 1–4 as unimolecular photoinitiators for styrene “living” polymerization was proven to be difficult due to rapid quenching of the excited state of the initiator by this monomer. Compound 4 was demonstrated as an initiator for controlled photopolymerization of methyl methacrylate.

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Postnikov Pavel

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DSc in Chemistry

218 publications, 4 638 citations

h-index: 37

National Research Tomsk Polytechnic University

N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Metal-organic coordination polymers

Nanophotonics

Non-covalent Interactions

Organic Chemistry

Physical Chemistry

Plasmonics

Supramolecular chemistry

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GOST Copy

Hu S. et al. Exploring chromophore tethered aminoethers as potential photoinitiators for controlled radical polymerization // Polymer. 2000. Vol. 41. No. 2. pp. 445-452.

GOST all authors (up to 50) Copy

Hu S., Malpert J. H., Yang X., Neckers D. C. Exploring chromophore tethered aminoethers as potential photoinitiators for controlled radical polymerization // Polymer. 2000. Vol. 41. No. 2. pp. 445-452.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/S0032-3861(99)00188-3

UR - https://doi.org/10.1016/S0032-3861(99)00188-3

TI - Exploring chromophore tethered aminoethers as potential photoinitiators for controlled radical polymerization

T2 - Polymer

AU - Hu, S.

AU - Malpert, J H

AU - Yang, X.

AU - Neckers, D. C.

PY - 2000

DA - 2000/01/01

PB - Elsevier

SP - 445-452

IS - 2

VL - 41

SN - 0032-3861

SN - 1873-2291

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2000_Hu,

author = {S. Hu and J H Malpert and X. Yang and D. C. Neckers},

title = {Exploring chromophore tethered aminoethers as potential photoinitiators for controlled radical polymerization},

journal = {Polymer},

year = {2000},

volume = {41},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/S0032-3861(99)00188-3},

number = {2},

pages = {445--452},

doi = {10.1016/S0032-3861(99)00188-3}

}

MLA

Cite this

MLA Copy

Hu, S., et al. “Exploring chromophore tethered aminoethers as potential photoinitiators for controlled radical polymerization.” Polymer, vol. 41, no. 2, Jan. 2000, pp. 445-452. https://doi.org/10.1016/S0032-3861(99)00188-3.

Publisher

Elsevier

Journal

Polymer

scimago Q1

wos Q2

SJR

0.843

CiteScore

7.7

Impact factor

4.5

ISSN

00323861 (Print)

18732291