volume 54 issue 39 pages 11793-11812

Synthesis of polyazapolycyclic caged polynitramines

Arnold T Nielsen 1
Andrew P. Chafin 1
Stephen L Christian 1
Donald E. Moore 1
Melvin P Nadler 1
Robin A Nissan 1
David J Vanderah 1
Richard D. Gilardi 2
Clifford F. George 2
Judith L. Flippen-Anderson 2
1
 
Chemistry and Materials Branch, Research and Technology Group Naval Air Warfare Center Weapons Division, China Lake, CA 93555-6100, USA
Publication typeJournal Article
Publication date1998-09-01
scimago Q3
wos Q2
SJR0.426
CiteScore4.1
Impact factor2.2
ISSN00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Syntheses of new polyazapolycyclic caged polynitramines are described. Sequentially reacting 4,10-dibenzyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane ( 5a ) with NOBF 4 and NO 2 BF 4 in sulfolane solvent produces 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.0 5,9 .0 3,11 ]dodecane, 6 ). Syntheses of two new polyazapolycyclic caged trinitramines, 3,5,12-trinitro-3,5,12-triazawurtzitane ( 7a ) and 2,4,10-trinitro-2,4,10-triazaadamantane ( 12a ), as well as their labile parent secondary amines, are discussed. A new caged polynitrosamine, 3,5,12-trinitroso-3,5,12-triazawurtzitane ( 7d ), has been obtained by ring-cleavage nitrosation of the new hexamine-wurtzitane compound 3,5,7,9-tetraazahexacyclo-[9.3.1.1 3,7 .0 2,9 .0 4,13 .0 5,10 ]-hexadecane ( 10 ). The synthesis of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.0 5,9 .0 3,11 ]dodecane, 2,4,10-trinitro-2,4,10-triazaadamantane and 3,5,12-trinitroso-3,5,12-triazawurtzitane are reported.
Found 
Found 

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GOST |
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GOST Copy
Nielsen A. T. et al. Synthesis of polyazapolycyclic caged polynitramines // Tetrahedron. 1998. Vol. 54. No. 39. pp. 11793-11812.
GOST all authors (up to 50) Copy
Nielsen A. T., Chafin A. P., Christian S. L., Moore D. E., Nadler M. P., Nissan R. A., Vanderah D. J., Gilardi R. D., George C. F., Flippen-Anderson J. L. Synthesis of polyazapolycyclic caged polynitramines // Tetrahedron. 1998. Vol. 54. No. 39. pp. 11793-11812.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/S0040-4020(98)83040-8
UR - https://doi.org/10.1016/S0040-4020(98)83040-8
TI - Synthesis of polyazapolycyclic caged polynitramines
T2 - Tetrahedron
AU - Nielsen, Arnold T
AU - Chafin, Andrew P.
AU - Christian, Stephen L
AU - Moore, Donald E.
AU - Nadler, Melvin P
AU - Nissan, Robin A
AU - Vanderah, David J
AU - Gilardi, Richard D.
AU - George, Clifford F.
AU - Flippen-Anderson, Judith L.
PY - 1998
DA - 1998/09/01
PB - Elsevier
SP - 11793-11812
IS - 39
VL - 54
SN - 0040-4020
SN - 1464-5416
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1998_Nielsen,
author = {Arnold T Nielsen and Andrew P. Chafin and Stephen L Christian and Donald E. Moore and Melvin P Nadler and Robin A Nissan and David J Vanderah and Richard D. Gilardi and Clifford F. George and Judith L. Flippen-Anderson},
title = {Synthesis of polyazapolycyclic caged polynitramines},
journal = {Tetrahedron},
year = {1998},
volume = {54},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/S0040-4020(98)83040-8},
number = {39},
pages = {11793--11812},
doi = {10.1016/S0040-4020(98)83040-8}
}
MLA
Cite this
MLA Copy
Nielsen, Arnold T., et al. “Synthesis of polyazapolycyclic caged polynitramines.” Tetrahedron, vol. 54, no. 39, Sep. 1998, pp. 11793-11812. https://doi.org/10.1016/S0040-4020(98)83040-8.