volume 38 issue 30 pages 5339-5342

A simple and practical approach to the synthesis of the marine sponge pigment fascaplysin and related compounds

Publication typeJournal Article
Publication date1997-07-01
scimago Q3
wos Q3
SJR0.334
CiteScore3.2
Impact factor1.5
ISSN00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Fascaplysin 1, an antimicrobial and cytotoxic red pigment of the marine sponge Fascaplys-inopsis sp., has been synthesized in five steps from tryptamine 2 in 44% overall yield. The key steps in the synthesis are: (a) dehydrogenation of the dihydro-β-carboline intermediate 4 simultaneously with its benzylic oxidation on treatment with MnO2 and (b) the thermal cyclization of the resulting β-carboline 7 into a quaternary salt 8. Similarly, indoloisoquinolines 15 and 16, the tetracyclic analogues of 1, were prepared in six steps from α-amino ketone 9 in 59 and 55% overall yields, respectively.
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GOST Copy
Radchenko O. S., Novikov V. L., Elyakov G. B. A simple and practical approach to the synthesis of the marine sponge pigment fascaplysin and related compounds // Tetrahedron Letters. 1997. Vol. 38. No. 30. pp. 5339-5342.
GOST all authors (up to 50) Copy
Radchenko O. S., Novikov V. L., Elyakov G. B. A simple and practical approach to the synthesis of the marine sponge pigment fascaplysin and related compounds // Tetrahedron Letters. 1997. Vol. 38. No. 30. pp. 5339-5342.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/S0040-4039(97)01167-2
UR - https://doi.org/10.1016/S0040-4039(97)01167-2
TI - A simple and practical approach to the synthesis of the marine sponge pigment fascaplysin and related compounds
T2 - Tetrahedron Letters
AU - Radchenko, Oleg S
AU - Novikov, Vyacheslav L
AU - Elyakov, George B.
PY - 1997
DA - 1997/07/01
PB - Elsevier
SP - 5339-5342
IS - 30
VL - 38
SN - 0040-4039
SN - 1873-3581
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1997_Radchenko,
author = {Oleg S Radchenko and Vyacheslav L Novikov and George B. Elyakov},
title = {A simple and practical approach to the synthesis of the marine sponge pigment fascaplysin and related compounds},
journal = {Tetrahedron Letters},
year = {1997},
volume = {38},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/S0040-4039(97)01167-2},
number = {30},
pages = {5339--5342},
doi = {10.1016/S0040-4039(97)01167-2}
}
MLA
Cite this
MLA Copy
Radchenko, Oleg S., et al. “A simple and practical approach to the synthesis of the marine sponge pigment fascaplysin and related compounds.” Tetrahedron Letters, vol. 38, no. 30, Jul. 1997, pp. 5339-5342. https://doi.org/10.1016/S0040-4039(97)01167-2.