Sulfonation of alkenes with sulfur trioxide; stereospecific β-sultone formation
Publication type: Journal Article
Publication date: 1987-01-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Sulfonation of 1-octene, ( E )-1-deuterio-1-octene, and ( Z )- and ( E )-4-octene with one mol-equiv of sulfur trioxide yields the β-sultones 2a - d respectively. The reaction proceeds stereospecifically via a concerted cis -cycloaddition. The sulfonation of both terminal and internal linear olefins yiels β-sultone in a stereospecific manner, as was shown for e . g . R 1 = 1-hexyl, R 2 = R 4 = H, R 3 = 2 H.
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GOST
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Bakker B., Cerfontain H. Sulfonation of alkenes with sulfur trioxide; stereospecific β-sultone formation // Tetrahedron Letters. 1987. Vol. 28. No. 15. pp. 1699-1702.
GOST all authors (up to 50)
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Bakker B., Cerfontain H. Sulfonation of alkenes with sulfur trioxide; stereospecific β-sultone formation // Tetrahedron Letters. 1987. Vol. 28. No. 15. pp. 1699-1702.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0040-4039(00)95398-X
UR - https://doi.org/10.1016/S0040-4039(00)95398-X
TI - Sulfonation of alkenes with sulfur trioxide; stereospecific β-sultone formation
T2 - Tetrahedron Letters
AU - Bakker, Bert
AU - Cerfontain, Hans
PY - 1987
DA - 1987/01/01
PB - Elsevier
SP - 1699-1702
IS - 15
VL - 28
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1987_Bakker,
author = {Bert Bakker and Hans Cerfontain},
title = {Sulfonation of alkenes with sulfur trioxide; stereospecific β-sultone formation},
journal = {Tetrahedron Letters},
year = {1987},
volume = {28},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0040-4039(00)95398-X},
number = {15},
pages = {1699--1702},
doi = {10.1016/S0040-4039(00)95398-X}
}
Cite this
MLA
Copy
Bakker, Bert H., et al. “Sulfonation of alkenes with sulfur trioxide; stereospecific β-sultone formation.” Tetrahedron Letters, vol. 28, no. 15, Jan. 1987, pp. 1699-1702. https://doi.org/10.1016/S0040-4039(00)95398-X.