Synthesis and reactivity of gem-dimetallic organic compounds. Part 1
1
Laboratoire de Chimie des Organo-éléments, tour 44 Université P. & M. Curie, 4 place Jussieu 75252 PARIS Cédex 05 France
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Publication type: Journal Article
Publication date: 1986-01-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Summary A number of gem-dimetallic compounds 4a-i have been prepared by carbometallation of an alkenyl organometallic derivative of Mg, Li or Al by an allylic zinc bromide. The 1-magnesia-1-zincaalkenes 4a-b react smoothly with various aldehydes in the presence of βF 3 .Oɛt 2 to furnish (ɛ)-1,5-dienes in high yields and high isomeric purity.
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69
Total citations:
69
Citations from 2024:
2
(2%)
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GOST
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Knochel P., Normant J. F. Synthesis and reactivity of gem-dimetallic organic compounds. Part 1 // Tetrahedron Letters. 1986. Vol. 27. No. 9. pp. 1039-1042.
GOST all authors (up to 50)
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Knochel P., Normant J. F. Synthesis and reactivity of gem-dimetallic organic compounds. Part 1 // Tetrahedron Letters. 1986. Vol. 27. No. 9. pp. 1039-1042.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0040-4039(86)80042-9
UR - https://doi.org/10.1016/S0040-4039(86)80042-9
TI - Synthesis and reactivity of gem-dimetallic organic compounds. Part 1
T2 - Tetrahedron Letters
AU - Knochel, Paul
AU - Normant, J F
PY - 1986
DA - 1986/01/01
PB - Elsevier
SP - 1039-1042
IS - 9
VL - 27
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1986_Knochel,
author = {Paul Knochel and J F Normant},
title = {Synthesis and reactivity of gem-dimetallic organic compounds. Part 1},
journal = {Tetrahedron Letters},
year = {1986},
volume = {27},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/S0040-4039(86)80042-9},
number = {9},
pages = {1039--1042},
doi = {10.1016/S0040-4039(86)80042-9}
}
Cite this
MLA
Copy
Knochel, P., et al. “Synthesis and reactivity of gem-dimetallic organic compounds. Part 1.” Tetrahedron Letters, vol. 27, no. 9, Jan. 1986, pp. 1039-1042. https://doi.org/10.1016/S0040-4039(86)80042-9.