Enantiomerically pure 1,2,5-triphenylphospholane through the synthesis and resolution of the chiral trans-(2,5)-diphenylphospholanic acid
Publication type: Journal Article
Publication date: 1999-04-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
The synthesis and resolution of trans -(2,5)-diphenylphospholanic acid 7 is described. The phosphinic acid 7 was converted into optically active (1,2,5)-triphenylphospholane 5 which was used as a chiral ligand in Rh-catalyzed hydrogenation of N -acetyl dehydrophenylalanine methyl ester to give quantitative yield of methyl N-acetylphenylalaninate with 82 % e.e.
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Total citations:
83
Citations from 2024:
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(3%)
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GOST
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Guillen F., Fiaud J. Enantiomerically pure 1,2,5-triphenylphospholane through the synthesis and resolution of the chiral trans-(2,5)-diphenylphospholanic acid // Tetrahedron Letters. 1999. Vol. 40. No. 15. pp. 2939-2942.
GOST all authors (up to 50)
Copy
Guillen F., Fiaud J. Enantiomerically pure 1,2,5-triphenylphospholane through the synthesis and resolution of the chiral trans-(2,5)-diphenylphospholanic acid // Tetrahedron Letters. 1999. Vol. 40. No. 15. pp. 2939-2942.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0040-4039(99)00329-9
UR - https://doi.org/10.1016/S0040-4039(99)00329-9
TI - Enantiomerically pure 1,2,5-triphenylphospholane through the synthesis and resolution of the chiral trans-(2,5)-diphenylphospholanic acid
T2 - Tetrahedron Letters
AU - Guillen, Frédéric
AU - Fiaud, Jean-Claude
PY - 1999
DA - 1999/04/01
PB - Elsevier
SP - 2939-2942
IS - 15
VL - 40
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1999_Guillen,
author = {Frédéric Guillen and Jean-Claude Fiaud},
title = {Enantiomerically pure 1,2,5-triphenylphospholane through the synthesis and resolution of the chiral trans-(2,5)-diphenylphospholanic acid},
journal = {Tetrahedron Letters},
year = {1999},
volume = {40},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/S0040-4039(99)00329-9},
number = {15},
pages = {2939--2942},
doi = {10.1016/S0040-4039(99)00329-9}
}
Cite this
MLA
Copy
Guillen, Frédéric, and Jean-Claude Fiaud. “Enantiomerically pure 1,2,5-triphenylphospholane through the synthesis and resolution of the chiral trans-(2,5)-diphenylphospholanic acid.” Tetrahedron Letters, vol. 40, no. 15, Apr. 1999, pp. 2939-2942. https://doi.org/10.1016/S0040-4039(99)00329-9.