Polyhedron

, том 11 , издание 22 , страницы 2877-2882

New oligomeric structures of barium dipivaloylmethanate, Ba4(thd)8, and its pivalate derivative Ba5(thd)9(piv)

Тип публикации: Journal Article

Дата публикации: 1992-01-01

Elsevier

Polyhedron

SCImago Q3

WOS Q2

БС2

SJR: 0.375

CiteScore: 5

Impact factor: 2.8

ISSN: 02775387, 18733719

DOI: 10.1016/S0277-5387(00)83590-1

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

The reaction of barium metal with Hthd in dry pentane results in the tetranuclear complex Ba4(thd)8 (I), which can be sublimed in vacuo. Using Hthd, containing a small amount of pivalic acid, the pentanuclear chelate Ba5(thd)9(piv) (II) was isolated. Crystal structure determination shows the rhomboid arrangement of barium atoms in I and square Ba4 units combined with Ba3 triangles in a common side in II. All thd ligands in I are monochelating and differ only by the number of additional OBa bonds. In structure II, besides this type of coordination, a new bichelating coordination mode of β-diketonate ligands has been found.

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Drozdov A., Trojanov S. I. New oligomeric structures of barium dipivaloylmethanate, Ba4(thd)8, and its pivalate derivative Ba5(thd)9(piv) // Polyhedron. 1992. Vol. 11. No. 22. pp. 2877-2882.

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Drozdov A., Trojanov S. I. New oligomeric structures of barium dipivaloylmethanate, Ba4(thd)8, and its pivalate derivative Ba5(thd)9(piv) // Polyhedron. 1992. Vol. 11. No. 22. pp. 2877-2882.

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TY - JOUR

DO - 10.1016/S0277-5387(00)83590-1

UR - https://doi.org/10.1016/S0277-5387(00)83590-1

TI - New oligomeric structures of barium dipivaloylmethanate, Ba4(thd)8, and its pivalate derivative Ba5(thd)9(piv)

T2 - Polyhedron

AU - Drozdov, A.A.

AU - Trojanov, S I

PY - 1992

DA - 1992/01/01

PB - Elsevier

SP - 2877-2882

IS - 22

VL - 11

SN - 0277-5387

SN - 1873-3719

ER -

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@article{1992_Drozdov,

author = {A.A. Drozdov and S I Trojanov},

title = {New oligomeric structures of barium dipivaloylmethanate, Ba4(thd)8, and its pivalate derivative Ba5(thd)9(piv)},

journal = {Polyhedron},

year = {1992},

volume = {11},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/S0277-5387(00)83590-1},

number = {22},

pages = {2877--2882},

doi = {10.1016/S0277-5387(00)83590-1}

}

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Drozdov, A.A., and S I Trojanov. “New oligomeric structures of barium dipivaloylmethanate, Ba4(thd)8, and its pivalate derivative Ba5(thd)9(piv).” Polyhedron, vol. 11, no. 22, Jan. 1992, pp. 2877-2882. https://doi.org/10.1016/S0277-5387(00)83590-1.

Издатель

Elsevier

Журнал

Polyhedron

SCImago Q3

WOS Q2

БС2

SJR

0.375

CiteScore

Impact factor

2.8