Palladium co-ordination chemistry of β-diimines: a preparative and structural comparison with α-diimines
Elaine K. Cope-Eatough
1
,
Francis S. Mair
2
,
R. G. Pritchard
2
,
John K. John Warren
2
,
Rebecca Woods
1, 3
1
Department of Chemistry, UMIST, Manchester, M60 1QD, UK
|
2
Department of Chemistry, UMIST, Manchester M60 1QD, UK
|
Publication type: Journal Article
Publication date: 2003-06-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The co-ordination chemistry of β-diimines has been found to be markedly different from otherwise identical α-diimines, it being significantly more difficult to prepare stable complexes of a variety of transition metal species. Where such species were preparable, the ligands were found to be incapable of stabilising metal–alkyl bonds, in marked contrast to their α-diimine counterparts. These differences are ascribed to a combination of steric, entropic and electronic factors. Crystal structures of 2-Pri-C6H4NCMeCMe2CMeN-2-Pri-C6H4, 2,6-Pri 2-C6H3NCMeCMeN-2-Pri-C6H4, [2-Pri-C6H4NCMeCMe2CMeN-2-Pri-C6H4PdCl2] and [2,6-Pri 2-C6H3NCMeCMeN-2,6-Pri-C6H3PdCl2] are reported. A partial structure of [2,6-Pri 2-C6H3NCMeCMe2CMeN-2,6-Pri-C6H3Pd2Cl4] is also briefly discussed.
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GOST
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Cope-Eatough E. K. et al. Palladium co-ordination chemistry of β-diimines: a preparative and structural comparison with α-diimines // Polyhedron. 2003. Vol. 22. No. 11. pp. 1447-1454.
GOST all authors (up to 50)
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Cope-Eatough E. K., Mair F. S., Pritchard R. G., John Warren J. K., Woods R. Palladium co-ordination chemistry of β-diimines: a preparative and structural comparison with α-diimines // Polyhedron. 2003. Vol. 22. No. 11. pp. 1447-1454.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0277-5387(03)00123-2
UR - https://doi.org/10.1016/S0277-5387(03)00123-2
TI - Palladium co-ordination chemistry of β-diimines: a preparative and structural comparison with α-diimines
T2 - Polyhedron
AU - Cope-Eatough, Elaine K.
AU - Mair, Francis S.
AU - Pritchard, R. G.
AU - John Warren, John K.
AU - Woods, Rebecca
PY - 2003
DA - 2003/06/01
PB - Elsevier
SP - 1447-1454
IS - 11
VL - 22
SN - 0277-5387
SN - 1873-3719
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Cope-Eatough,
author = {Elaine K. Cope-Eatough and Francis S. Mair and R. G. Pritchard and John K. John Warren and Rebecca Woods},
title = {Palladium co-ordination chemistry of β-diimines: a preparative and structural comparison with α-diimines},
journal = {Polyhedron},
year = {2003},
volume = {22},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/S0277-5387(03)00123-2},
number = {11},
pages = {1447--1454},
doi = {10.1016/S0277-5387(03)00123-2}
}
Cite this
MLA
Copy
Cope-Eatough, Elaine K., et al. “Palladium co-ordination chemistry of β-diimines: a preparative and structural comparison with α-diimines.” Polyhedron, vol. 22, no. 11, Jun. 2003, pp. 1447-1454. https://doi.org/10.1016/S0277-5387(03)00123-2.