Polyhedron

, том 18 , издание 16 , страницы 2117-2127

Synthesis and NMR spectra of derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)nC6H6−n [n=2 to 4]

Тип публикации: Journal Article

Дата публикации: 1999-06-01

Elsevier

Polyhedron

SCImago Q3

WOS Q2

БС2

SJR: 0.375

CiteScore: 5

Impact factor: 2.8

ISSN: 02775387, 18733719

DOI: 10.1016/S0277-5387(99)00101-1

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Краткое описание

111 derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)nC6H6−n [n=2 to 4] obtained by oxidation or reaction with sulfur, selenium, iodomethane, M(CO)6 [M=Cr, Mo, W], [codRh-μ-Cl]2, or (PhCN)2MCl2 [M=Pd, Pt], are reported together with their 31P and selected other NMR parameters. The reactions generally follow predictable courses, although stereochemical factors affect the range of products obtained and can lead to significant structural distortion in extreme cases. The 31P chemical shifts and more particularly vicinal coupling constants are also markedly influenced by such factors, to the extent that in species with three or more adjacent Ph2P moieties they may be of limited diagnostic value.

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Mcfarlane H. C. E., McFarlane W. Synthesis and NMR spectra of derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)nC6H6−n [n=2 to 4] // Polyhedron. 1999. Vol. 18. No. 16. pp. 2117-2127.

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Mcfarlane H. C. E., McFarlane W. Synthesis and NMR spectra of derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)nC6H6−n [n=2 to 4] // Polyhedron. 1999. Vol. 18. No. 16. pp. 2117-2127.

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TY - JOUR

DO - 10.1016/S0277-5387(99)00101-1

UR - https://doi.org/10.1016/S0277-5387(99)00101-1

TI - Synthesis and NMR spectra of derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)nC6H6−n [n=2 to 4]

T2 - Polyhedron

AU - Mcfarlane, H Christina E

AU - McFarlane, William

PY - 1999

DA - 1999/06/01

PB - Elsevier

SP - 2117-2127

IS - 16

VL - 18

SN - 0277-5387

SN - 1873-3719

ER -

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@article{1999_Mcfarlane,

author = {H Christina E Mcfarlane and William McFarlane},

title = {Synthesis and NMR spectra of derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)nC6H6−n [n=2 to 4]},

journal = {Polyhedron},

year = {1999},

volume = {18},

publisher = {Elsevier},

month = {jun},

url = {https://doi.org/10.1016/S0277-5387(99)00101-1},

number = {16},

pages = {2117--2127},

doi = {10.1016/S0277-5387(99)00101-1}

}

MLA

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MLA Скопировать

Mcfarlane, H. Christina E., and William McFarlane. “Synthesis and NMR spectra of derivatives of the polykis(diphenylphosphino)benzenes, (Ph2P)nC6H6−n [n=2 to 4].” Polyhedron, vol. 18, no. 16, Jun. 1999, pp. 2117-2127. https://doi.org/10.1016/S0277-5387(99)00101-1.

Издатель

Elsevier

Журнал

Polyhedron

SCImago Q3

WOS Q2

БС2

SJR

0.375

CiteScore

Impact factor

2.8

ISSN

02775387 (Print)

18733719

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