XPS and UPS study of oxygen states on silver
Publication type: Journal Article
Publication date: 1998-11-01
scimago Q2
wos Q3
SJR: 0.601
CiteScore: 3.6
Impact factor: 1.5
ISSN: 03682048, 18732526
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Radiation
Abstract
An investigation of the nature of the silver–oxygen bond for different oxygen states on the silver surface has been carried out by XPS and UPS. The XPS analysis shows the Eb(O1s) to range from 528.0 to 534.0 eV, which is much wider than for other oxygen–metal systems. The low O1s binding energies with E b (O1s)=528.0−529.0 eV can be reliably related to atomic oxygen of oxide-like structures characterized by ionic O–Ag bonding. The higher binding energies indicate the covalent character of the Ag–O bond with no charge polarization. UPS allowed us to reveal five additional characteristics in the valence band after high-temperature oxygen treatment, when the oxygen states with E b (O1s)=530.4 eV appear in spectra. They are related to quasimolecular oxygen species. On the basis of these data, the quasimolecular character of the oxygen states with Eb(O1s)>530 eV is postulated. The experiments demonstrate an abnormally high thermal stability (Tdes>800 K) of these oxygen states. Some proposals to account for the results obtained are discussed.
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134
Total citations:
134
Citations from 2024:
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(21%)
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Boronin A., Koscheev S., Zhidomirov G. XPS and UPS study of oxygen states on silver // Journal of Electron Spectroscopy and Related Phenomena. 1998. Vol. 96. No. 1-3. pp. 43-51.
GOST all authors (up to 50)
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Boronin A., Koscheev S., Zhidomirov G. XPS and UPS study of oxygen states on silver // Journal of Electron Spectroscopy and Related Phenomena. 1998. Vol. 96. No. 1-3. pp. 43-51.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S0368-2048(98)00221-7
UR - https://doi.org/10.1016/S0368-2048(98)00221-7
TI - XPS and UPS study of oxygen states on silver
T2 - Journal of Electron Spectroscopy and Related Phenomena
AU - Boronin, Andrei
AU - Koscheev, S.V.
AU - Zhidomirov, G.M.
PY - 1998
DA - 1998/11/01
PB - Elsevier
SP - 43-51
IS - 1-3
VL - 96
SN - 0368-2048
SN - 1873-2526
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1998_Boronin,
author = {Andrei Boronin and S.V. Koscheev and G.M. Zhidomirov},
title = {XPS and UPS study of oxygen states on silver},
journal = {Journal of Electron Spectroscopy and Related Phenomena},
year = {1998},
volume = {96},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/S0368-2048(98)00221-7},
number = {1-3},
pages = {43--51},
doi = {10.1016/S0368-2048(98)00221-7}
}
Cite this
MLA
Copy
Boronin, Andrei, et al. “XPS and UPS study of oxygen states on silver.” Journal of Electron Spectroscopy and Related Phenomena, vol. 96, no. 1-3, Nov. 1998, pp. 43-51. https://doi.org/10.1016/S0368-2048(98)00221-7.
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