Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts
Publication type: Journal Article
Publication date: 2000-02-01
scimago Q1
wos Q1
SJR: 5.180
CiteScore: 38.4
Impact factor: 21.1
ISSN: 09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
Eight commercial catalysts (Nickel-Raney, Ni on SiO 2 , Pd on alumina, Pt on both alumina and activated carbon, Rh on alumina, Ru on alumina and sulfided Ni–Mo on alumina) were tested as catalysts for the hydrodechlorination of the six organochlorinated compounds that are released into the environment in the greatest amounts: dichloromethane, chloroform, carbon tetrachloride, 1,1,1-trichloroethane, trichloroethylene and tetrachloroethylene. Hydrodechlorination experiments were carried out in discontinuous micro-reactors at 50 bar of hydrogen and at 300°C, and during reaction times of 30, 60 and 90 min, using 4 vol% solutions of the organochlorinated compounds in heptane. Pt catalysts were found to yield the highest conversions for the reactions studied.
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GOST
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Ordóñez S. G., Sastre H., Dı́ez F. V. Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts // Applied Catalysis B: Environmental. 2000. Vol. 25. No. 1. pp. 49-58.
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Ordóñez S. G., Sastre H., Dı́ez F. V. Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts // Applied Catalysis B: Environmental. 2000. Vol. 25. No. 1. pp. 49-58.
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RIS
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TY - JOUR
DO - 10.1016/S0926-3373(99)00119-8
UR - https://doi.org/10.1016/S0926-3373(99)00119-8
TI - Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts
T2 - Applied Catalysis B: Environmental
AU - Ordóñez, Salvador Gutiérrez
AU - Sastre, Herminio
AU - Dı́ez, Fernando V.
PY - 2000
DA - 2000/02/01
PB - Elsevier
SP - 49-58
IS - 1
VL - 25
SN - 0926-3373
SN - 1873-3883
ER -
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BibTex (up to 50 authors)
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@article{2000_Ordóñez,
author = {Salvador Gutiérrez Ordóñez and Herminio Sastre and Fernando V. Dı́ez},
title = {Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts},
journal = {Applied Catalysis B: Environmental},
year = {2000},
volume = {25},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/S0926-3373(99)00119-8},
number = {1},
pages = {49--58},
doi = {10.1016/S0926-3373(99)00119-8}
}
Cite this
MLA
Copy
Ordóñez, Salvador Gutiérrez, et al. “Hydrodechlorination of aliphatic organochlorinated compounds over commercial hydrogenation catalysts.” Applied Catalysis B: Environmental, vol. 25, no. 1, Feb. 2000, pp. 49-58. https://doi.org/10.1016/S0926-3373(99)00119-8.