Giant Pd-561 clusters: Onset to new catalytic properties
1
Syntez Research Institute, Joint-Stock, 293760 Boryslav, Ukraine
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Publication type: Journal Article
Publication date: 1999-10-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 13811169
Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology
Abstract
Remarkable catalytic properties have been exhibited by giant Pd-561 clusters (GPC) employed in oxidation reactions. Lower alcohol oxidation can easily occur in GPC solution at 293–323 K giving wide product spectrum: aldehydes, esters, anhydrides, carboxylic acids and acetals. Moreover hydrocarbons and carbon dioxide have been found as gaseous products. Actually GPC imply some reactivity of both bulk Pd and Pd complexes. This reactivity, however, acquires new unique features unknown for any other clusters or Pd compounds. Reaction mechanism involves formation of two kinds of activated species. It also assumes the reaction medium as well as ligand sphere to be of significant importance for GPC reactivity.
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15
Total citations:
15
Citations from 2024:
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MLA
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GOST
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Starchevsky M. K. et al. Giant Pd-561 clusters: Onset to new catalytic properties // Journal of Molecular Catalysis A Chemical. 1999. Vol. 146. No. 1-2. pp. 229-236.
GOST all authors (up to 50)
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Starchevsky M. K., Hladiy S. L., Pazdersky Y. A., Vargaftik M. N., Moiseev I. I. Giant Pd-561 clusters: Onset to new catalytic properties // Journal of Molecular Catalysis A Chemical. 1999. Vol. 146. No. 1-2. pp. 229-236.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/S1381-1169(99)00086-2
UR - https://linkinghub.elsevier.com/retrieve/pii/S1381116999000862
TI - Giant Pd-561 clusters: Onset to new catalytic properties
T2 - Journal of Molecular Catalysis A Chemical
AU - Starchevsky, Mykhailo K.
AU - Hladiy, Serhiy L
AU - Pazdersky, Yuriy A.
AU - Vargaftik, Mikhail N
AU - Moiseev, Illia I
PY - 1999
DA - 1999/10/01
PB - Elsevier
SP - 229-236
IS - 1-2
VL - 146
SN - 1381-1169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1999_Starchevsky,
author = {Mykhailo K. Starchevsky and Serhiy L Hladiy and Yuriy A. Pazdersky and Mikhail N Vargaftik and Illia I Moiseev},
title = {Giant Pd-561 clusters: Onset to new catalytic properties},
journal = {Journal of Molecular Catalysis A Chemical},
year = {1999},
volume = {146},
publisher = {Elsevier},
month = {oct},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1381116999000862},
number = {1-2},
pages = {229--236},
doi = {10.1016/S1381-1169(99)00086-2}
}
Cite this
MLA
Copy
Starchevsky, Mykhailo K., et al. “Giant Pd-561 clusters: Onset to new catalytic properties.” Journal of Molecular Catalysis A Chemical, vol. 146, no. 1-2, Oct. 1999, pp. 229-236. https://linkinghub.elsevier.com/retrieve/pii/S1381116999000862.
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