Copper (II) chloride–dmf catalytic system in solution and on silica
Publication type: Journal Article
Publication date: 1999-10-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 13811169
Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology
Abstract
The connections between composition and formation conditions of catalysts based on immobilised complexes of Cu(II) and dmf as precursors and their catalytic activity in C–Cl bond metathesis in system CCl 4 – n -C 10 H 22 were studied. High activity and selectivity could be obtained providing that a lamina of dmf containing mononuclear copper complexes forms in pores of a support. It was shown that the composition and structure of surface complexes does not depend on concentrations of copper ions or dmf in precursor solution. The loss of catalytic activity when the support cannot fix the lamina (e.g., charcoal in contrast with silica) is observed. The key stage of catalysis could be a reduction of Cu(II) to Cu(I).
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Total citations:
7
Citations from 2024:
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GOST
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Golubeva E. N. et al. Copper (II) chloride–dmf catalytic system in solution and on silica // Journal of Molecular Catalysis A Chemical. 1999. Vol. 146. No. 1-2. pp. 343-350.
GOST all authors (up to 50)
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Golubeva E. N., Kokorin A. I., Zubareva N. A., Vorontsov P. S., Smirnov V. V. Copper (II) chloride–dmf catalytic system in solution and on silica // Journal of Molecular Catalysis A Chemical. 1999. Vol. 146. No. 1-2. pp. 343-350.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S1381-1169(99)00276-9
UR - https://doi.org/10.1016/S1381-1169(99)00276-9
TI - Copper (II) chloride–dmf catalytic system in solution and on silica
T2 - Journal of Molecular Catalysis A Chemical
AU - Golubeva, Elena N
AU - Kokorin, Alexander I.
AU - Zubareva, N A
AU - Vorontsov, P S
AU - Smirnov, V. V.
PY - 1999
DA - 1999/10/01
PB - Elsevier
SP - 343-350
IS - 1-2
VL - 146
SN - 1381-1169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1999_Golubeva,
author = {Elena N Golubeva and Alexander I. Kokorin and N A Zubareva and P S Vorontsov and V. V. Smirnov},
title = {Copper (II) chloride–dmf catalytic system in solution and on silica},
journal = {Journal of Molecular Catalysis A Chemical},
year = {1999},
volume = {146},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/S1381-1169(99)00276-9},
number = {1-2},
pages = {343--350},
doi = {10.1016/S1381-1169(99)00276-9}
}
Cite this
MLA
Copy
Golubeva, Elena N., et al. “Copper (II) chloride–dmf catalytic system in solution and on silica.” Journal of Molecular Catalysis A Chemical, vol. 146, no. 1-2, Oct. 1999, pp. 343-350. https://doi.org/10.1016/S1381-1169(99)00276-9.
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